Petrogenesis of Late Mesozoic Granites in Northwest Zhejiang
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摘要: 浙西北地区晚中生代处于环太平洋活动大陆边缘，区内岩浆侵入活动强烈，发育Ⅰ型和铝质A型两类花岗岩，前者又分为低分异Ⅰ型（简称Ⅰ型）和高分异Ⅰ型花岗岩两种，形成时限为中侏罗世-早白垩世早期（172~135 Ma），其中高分异Ⅰ型花岗岩集中于早白垩世早期（147~135 Ma）；铝质A型花岗岩形成于早白垩世中期（135~123 Ma）.同位素地球化学研究表明，中侏罗世-早白垩世早期Ⅰ型花岗岩（87Sr/86Sr）i值为0.707 004~0.711 896，εNd（t）值为-6.70~-2.00，锆石εHf（t）值为-5.08~-1.67，TDMC值为1 162~1 358 Ma，系古太平洋板块俯冲挤压的构造环境下，少量幔源物质沿变向俯冲引起的板片裂隙（窗）与下地壳重熔岩浆混合作用的产物；晚侏罗世末期-早白垩世早期高分异Ⅰ型花岗岩（87Sr/86Sr）i为0.706 890~ 0.709 880，εNd（t）值为-6.80~-4.50，锆石εHf（t）为-6.59~-5.23，TDMC为1 350~1 423 Ma，是古太平洋板块撤离机制下挤压向伸展转换的产物，系软流圈上涌诱发的幔源基性岩浆与中元古代地壳物质的部分熔融形成长英质岩浆混合并经高程度分异演化形成；早白垩世中期铝质A型花岗岩（87Sr/86Sr）i值为0.703 503~0.710 171，εNd（t）值为-8.90~-0.30，锆石εHf（t）值为-9.70~2.48，TDMC值为734~1 593 Ma，为岩石圈持续减薄机制下，越来越多的幔源物质（或新生地壳）涌入深部长英质岩浆房混合形成.Abstract: The strong Late Mesozoic magmatic intruding events happened in Northwest Zhejiang area, which is located in the active western Pacific margin. The granites are classified as Ⅰ- and aluminous A-types, and the former is further divided into Ⅰ-type and highly fractionated Ⅰ-type granites. The Ⅰ-type granites of Mid-Late Jurassic to early Early Cretaceous(172-135 Ma) have the initial 87Sr/86Sr ratios ranging from 0.707 004 to 0.711 896, εNd(t) values from -6.70 to -2.00, εHf(t) values from -5.08 to -1.67, indicating that these granites are originated from mixing between remelted Meso-Neoproterozoic Jiangnan island arc and little mantle materials rose along slab crack. The formation of these granites may be closely related to the subduction of Paleo-Pacific plate. The highly fractionated Ⅰ-type granites in the early Early Cretaceous(147-135 Ma) have the initial 87Sr/86Sr ratio ranging from 0.706 890 to 0.709 880, εNd(t) values from -6.80 to -4.50, εHf(t) values from -6.59 to -5.23, suggesting that they are the products of magma mixing by remelting crustal materials of the Meso-Neoproterozoic and rising mantle mafic magma due to asthenosphere uplifting. It also indicates that the tectonic environment transformed from compression to extension in this period.The A-type granites of middle Early Cretaceous(135-123 Ma) have the initial 87Sr/86Sr ratios ranging from 0.703 503 to 0.710 171, εNd(t) values from -8.90 to -0.30, εHf(t) values from -9.70 to 2.48, indicating that the magma during Middle-Early Cretaceous was mainly originated from remelting of the Meso-Neoproterozoic crustal materials, mixed by more and more mantle materials, in an extension setting.
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Key words:
- tectonic dynamic setting /
- petrogenesis /
- geochemistry /
- granite /
- Late Mesozoic /
- Northwest Zhejiang
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图 1 浙西北地区晚中生代花岗岩分布
Fig. 1. Distribution of Late-Mesozoic granites in Northwest Zhejiang
图 2 浙西北地区晚中生代花岗岩Na2O+K2O-SiO2(a)及K2O-SiO2(b)图解
据Rickwood(1989).Ⅰ1类花岗岩(172~135 Ma)唐燕文等(2012)、张建芳等(2013)、厉子龙等(2013)、Li et al.(2013)、王科强(2015)、胡开明等(2016)、唐增才等(2014, 2016, 2018)、唐增才(2016)、浙江省第三地质大队(2013, 江绍拼合带中西段铜多金属矿床区域成矿规律研究与成矿预测)、浙江省地质调查院(2015, 浙江1:5万杭垓、仙霞、船村幅区域地质矿产调查成果报告)、浙江省地质调查院(2011, 淳安唐村-临岐地区区域地质矿产调查成果报告)和浙江省地质调查院(2014, 开化杨林-淳安叶村地区矿产远景调查成果报告)；Ⅰ2类花岗岩(147~135 Ma)张建芳等(2013)和唐增才(2016)；Ⅱ类花岗岩(135~123 Ma)引自Jiang et al.(2011)、Li et al.(2013)、张建芳等(2015)和唐增才等(2016, 2017, 2018)
Fig. 2. Na2O+K2O vs. SiO2 diagram (a) and K2O vs. SiO2 diagram (b) for Late Mesozoic granites in Northwest Zhejiang
图 3 浙西北地区晚中生代花岗岩Harker图解
数据来源同图 2
Fig. 3. Hacker diagrams for Late Mesozoic granites in Northwest Zhejiang
图 4 浙西北地区晚中生代花岗岩A.R.-SiO2(a)及A/CNK-A/NK(b)图解
图a据Wright(1969)；图b据Maniar(1989).数据来源同图 2
Fig. 4. SiO2 vs. A.R diagram (a) and A/CNK vs. A/NK diagram (b) for Late Mesozoic granites in Northwest Zhejiang
图 5 浙西北地区晚中生代花岗岩稀土元素球粒陨石标准化曲线(a, c)和微量元素蛛网图(b, d)
标准值据Sun and McDonough(1989)；数据来源同图 2
Fig. 5. Chondrite-normalized REE patterns (a, c) and trace element spider diagrams (b, d) for Late Mesozoic granites in Northwest Zhejiang
图 6 浙西北地区晚中生代花岗岩(87Sr/86Sr)i-t和εNd(t)-t图解
MORB据夏林圻等(2004); 扬子下地壳、江南造山带东部地壳据Jiang et al.(2011)和Wang et al.(2012); 扬子上地壳据王元龙等(2004)
Fig. 6. (87Sr/86Sr)i-t diagram and εNd(t)-t diagram for Late Mesozoic granites in Northwest Zhejiang
图 7 浙西北地区晚中生代花岗岩Hf同位素演化图解
Fig. 7. Hf isotopic diagram for Late Mesozoic granites in Northwest Zhejiang
图 8 浙西北地区晚中生代花岗岩成因类型判别图解
图a据Frost et al.(2001)；图b据Wolf and London(1994)；图c~f据Whalen et al.(1987)
Fig. 8. Origin and classification diagrams for Late Mesozoic granites in Northwest Zhejiang
图 9 浙西北地区晚中生代花岗岩构造环境判别图解
图a~d据Pearce et al.(1984)；图e, f据Harris et al.(1986)
Fig. 9. Discrimination diagrams of tectonic setting for Late Mesozoic granites in Northwest Zhejiang
表 1 浙西北地区晚中生代花岗岩成岩年龄
Table 1. The formation age of the Late Mesozoic granites in Northwest Zhejiang
成岩阶段及分类 岩体位置 编号 测试对象 成岩年龄(Ma) 测试方法 资料来源 中晚侏罗世-早白垩世早期 Ⅰ型
I1类开化桐村 1 花岗斑岩 167.6~155.6 锆石U-Pb LA-ICP-MS 邱骏挺等, 2011 开化桐村 1 花岗斑岩 168.7~162.6 锆石U-Pb SHRIMP 王科强, 2015 开化桐村 2 花岗闪长岩 165.7~162.1 锆石U-Pb SHRIMP 王科强, 2015 常山兰花坞 3 花岗斑岩 172.0±3.4 锆石U-Pb SHRIMP 浙江省第三地质大队① 常山兰花坞 4 花岗闪长岩 162.3±0.9 锆石U-Pb SHRIMP 浙江省第三地质大队① 淳安大铜坑 5 花岗闪长岩 148.3±1.9 锆石U-Pb SHRIMP 胡开明等, 2016 淳安结蒙 6 花岗闪长岩 147.3±1.0 锆石U-Pb LA-ICP-MS Li et al., 2013 建德岭后 7 花岗闪长岩 169.9±1.4 锆石U-Pb LA-ICP-MS 贾少华等, 2014 建德岭后 7 花岗闪长岩 162.9±1.9 锆石U-Pb SHRIMP 王科强, 2015 淳安开岭脚 8 花岗闪长岩 151±3 锆石U-Pb SHRIMP 汪建国等, 2010 淳安里陈家 9 花岗闪长岩 148±2 锆石U-Pb SHRIMP 汪建国等, 2010 临安赤石 10 花岗闪长岩 147.2±1.0 锆石U-Pb LA-ICP-MS Wu et al., 2012 桐庐彰坞 11 花岗闪长岩 159.7±2.6 锆石U-Pb LA-ICP-MS 唐增才, 2016 绍兴珊溪 12 花岗闪长岩 150.1±2.6 锆石U-Pb LA-ICP-MS 顾明光等, 2011 富阳千家 13 花岗闪长岩 146.8±2.1 锆石U-Pb SHRIMP 唐增才等, 2016 余杭中泰 14 花岗闪长岩 144.9±1.5 锆石U-Pb LA-ICP-MS 刘荣，未发表 余杭闲林 15 花岗闪长岩 151.8±2.2 锆石U-Pb SHRIMP 唐增才等, 2014 德清何村 16 石英二长岩 149.2±1.1 锆石U-Pb LA-ICP-MS 唐增才等, 2018 安吉唐舍 17 二长花岗岩 140.4±3.3 锆石U-Pb LA-ICP-MS 浙江省地质调查院② 余杭长乐 18 二长花岗岩 138.8±1.9 锆石U-Pb SHRIMP 唐增才等，2016 富阳拔山 19 二长花岗岩 137.3±1.7 锆石U-Pb SHRIMP 唐增才等，2016 高分异
Ⅰ型I2类湖州康山 20 二长花岗岩 137.4±1.2 锆石U-Pb LA-ICP-MS 唐增才等, 2018 安吉马鞍山 21 二长花岗岩 138.0~129.7 锆石U-Pb LA-ICP-MS 陈芳等, 2014；张建芳等, 2015 安吉章村 22 二长花岗岩 145.1~144.2 锆石U-Pb LA-ICP-MS 张建芳等, 2017 安吉坞山关 23 二长花岗岩 141.0~139.2 锆石U-Pb LA-ICP-MS 唐燕文等，2013 临安学川 24 二长花岗岩 136.8±1.9 锆石U-Pb LA-ICP-MS Wu et al., 2012 诸暨广山 25 花岗岩 147.2±1.7 锆石U-Pb LA-ICP-MS 顾明光等, 2011 淳安木瓜 26 花岗斑岩 142.2±1.2 锆石U-Pb LA-ICP-MS 厉子龙等，2013 早白垩世中期 铝质
A型Ⅱ类常山岩前 27 二长花岗岩 127±2 锆石U-Pb SHRIMP 王科强, 2015 常山岩前 27 二长花岗岩 128.5±1.9 锆石U-Pb LA-ICP-MS 唐增才, 2016 衢州白菊花尖 28 正长花岗岩 125.6±3.2 锆石U-Pb LA-ICP-MS Wong et al., 2009 衢州九华山 29 正长花岗岩 135.1~132.4 锆石U-Pb LA-ICP-MS Yang et al., 2012 淳安儒洪 30 二长花岗岩 128.5±2.4 锆石U-Pb LA-ICP-MS Jiang et al., 2011 淳安儒洪 30 二长花岗岩 132±1 锆石U-Pb SHRIMP 王科强, 2015 淳安双溪口 31 二长花岗岩 130.4±1.1 锆石U-Pb LA-ICP-MS 唐增才等, 2017 淳安黄石潭 32 二长花岗岩 125.8±1.4 锆石U-Pb LA-ICP-MS Li et al., 2013 临安夏色岭 33 正长花岗岩 125.5~123.5 锆石U-Pb LA-ICP-MS 黄国成等, 2012a 桐庐合村 34 二长花岗岩 129.2±1.4 锆石U-Pb LA-ICP-MS Wu et al., 2012 临安河桥 35 二长花岗岩 126.8±1.6 锆石U-Pb LA-ICP-MS Wu et al., 2012 安吉章村 36 正长花岗岩 131.7~130.8 锆石U-Pb LA-ICP-MS 张建芳等, 2017 安吉唐舍 37 正长花岗岩 131.4±2.4 锆石U-Pb LA-ICP-MS Wu et al., 2012 安吉马鞍山 38 二长花岗岩 130~127 锆石U-Pb LA-ICP-MS Wu et al., 2012 安吉坞山关 39 正长花岗岩 134.5~133.9 锆石U-Pb LA-ICP-MS 谢玉玲等，2012b 余杭泗岭 40 正长花岗岩 131.3±1.7 锆石U-Pb LA-ICP-MS 唐增才等，2018 德清沈家墈 41 正长花岗岩 133.6±0.95 锆石U-Pb LA-ICP-MS 唐增才等，2018 德清莫干山 42 正长花岗岩 128.1±2.1 锆石U-Pb LA-ICP-MS 章邦桐等，2012 湖州凤凰山 43 正长花岗岩 131.7±1.5 锆石U-Pb LA-ICP-MS 唐增才等，2018 注：①浙江省第三地质大队, 2013, 江绍拼合带中西段铜多金属矿床区域成矿规律研究与成矿预测；②浙江省地质调查院, 2015, 浙江1:5万杭垓、仙霞、船村幅区域地质矿产调查成果报告. 
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