与海洋天然气水合物微纳米尺度赋存和开采储存技术有关的研究进展

樊栓狮; 于驰; 郎雪梅; 王燕鸿; 陈建标

doi:10.3799/dqkx.2018.412

与海洋天然气水合物微纳米尺度赋存和开采储存技术有关的研究进展

doi: 10.3799/dqkx.2018.412

樊栓狮^1,2, ,,
于驰^1,2,3,
郎雪梅^1,2,
王燕鸿^1,2,
陈建标^1,2

1.
华南理工大学化学与化工学院, 广东广州 510641
2.
华南理工大学传热强化与过程节能教育部重点实验室, 广东广州 510641
3.
中国科学院广州能源研究所天然气水合物重点实验室, 广东广州 510640

基金项目:

国家自然科学基金项目 51576069

国家自然科学基金项目 21736005

中国科学院天然气水合物重点实验室开放基金项目 Y607kg1001

详细信息

作者简介:
樊栓狮(1965-), 教授, 主要从事天然气水合物与能源新技术的研究

通讯作者:
樊栓狮

中图分类号: P618
计量
- 文章访问数: 5955
- HTML全文浏览量: 2389
- PDF下载量: 38
- 被引次数: 0
出版历程
- 收稿日期: 2017-10-01
- 刊出日期: 2018-05-15

Micro-Nano-Scale Studies on Occurrence and Gas Production and Storage Technology of Marine Gas Hydrates

Fan Shuanshi^{1,2
, ,},
Yu Chi^1,2,3,
Lang Xuemei^1,2,
Wang Yanhong^1,2,
Chen Jianbiao^1,2

1.
School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510641, China
2.
Key Lab of Enhanced Heat Transfer and Energy Conservation, Ministry of Education, South China University of Technology, Guangzhou 510641, China
3.
Key Laboratory of Gas Hydrate, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China

摘要

摘要: 天然气水合物是一类潜在的储量巨大的清洁能源.近年来，水合物的研究已经逐渐拓展至纳米、介观层面.纳米科学贯穿了水合物研究的全过程，包括上游天然气水合物成藏、开采和下游的储运、分离等水合物应用技术，其核心在于研究水合物在纳米材料表面、内部、间隙中生长和分解的传质传热过程.将以第九届国际水合物大会（ICGH9）为切入点，从水合物成藏、开采和下游技术应用几个方面综述近年来水合物研究中的纳米研究进展.目前对水合物的研究尺度并未做到全覆盖，水合物在纳米材料间隙中的传质传热过程研究较少，纳米材料的累积放大效应研究也存在空白.这正是水合物成藏、开采研究中的瓶颈问题.未来的研究应该着眼于水合物在纳米材料中生成和分解的传质传热作用，以此为主线将水合物技术和水合物成藏、开采研究中的核心问题进行统一协同研究.
- 天然气水合物 /
- 纳米 /
- 传质传热 /
- 赋存 /
- 开采 /
- 储存 /
- 二氧化碳封存 /
- 油气地质
Abstract: Natural gas hydrate is a kind of clean energy with potential huge reserves. Hydrate researches gradually extend to nano-and micro-scale recently. Nano science has been a part of hydrate researches, including occurrence, gas production and hydrate based technologies of downstream such as gas storage and separation. The common key is heat and mass transfer of hydrate formation and dissociation on the surface, inside and between nanomaterials. From 9th international conference on gas hydrates (ICGH9) as point of penetration in this paper, it reviews nano-scale studies on occurrence and gas production of marine gas hydrates, as well as downstream utilizations of gas hydrate technology.The results show that study of heat and mass transfer inside nanomaterial during hydrate formation and dissociation is needed to be developed. There is a blank area that accumulative effect of micro-nanomaterial during hydrate formation and dissociation. These questions have become bottleneck of gas hydrate occurrence and production. In the future, researches should focus on heat and mass transfer inside nanomaterial during hydrate formation and dissociation and use this as a link to systematively study occurrence and production of natural gas hydrates.
- natural gas hydrate /
- nano /
- mass and heat transfer /
- occurrence /
- gas production /
- gas storage /
- carbon dioxide storage /
- petroleum geology

HTML全文

图 1 中国南海某海域海底水合物矿样的SEM图和ESEM图

a~d.水合物矿样的SEM照片，放大倍数3万倍和6万倍；e，f.水合物矿样的ESEM照片，放大倍数2 000倍

Fig. 1. SEM and ESEM images of hydrate samples of the South China Sea

下载: 全尺寸图片幻灯片

图 2 水合物在纳米材料ZIF-8内部生长示意

据Zhang et al.(2015)

Fig. 2. Schematic of hydrate formation inside nanomaterial ZIF-8

下载: 全尺寸图片幻灯片

图 3 应用纳米材料ZIF-67浆液的水合物技术示意

据Pan et al.(2015)

Fig. 3. Hydrate-based technology by using nanomaterial ZIF-67 slurry

下载: 全尺寸图片幻灯片

表 1 测试SEM和ESEM的海底矿样信息

Table 1. Hydrate sample information of SEM and ESEM tests

样品名称	采样深度(m)	分析方法
S-10	124.65～125	SEM
S-26	133.5	SEM
S-31	135.1	SEM
S-40	160.8～160.9	SEM
S-1	148～148.8	ESEM
S-36	158.55～158.75	ESEM

下载: 导出CSV

参考文献(28)

Casco, M.E., Rey, F., Jordá, J.L., et al., 2016.Paving the Way for Methane Hydrate Formation on Metal-Organic Frameworks (MOFs).Chem.Sci., 7(6):3658-3666. https://doi.org/10.1039/C6SC00272B
Casco, M.E., Silvestre-Albero, J., Ramirez-Cuesta, A.J., et al., 2015.Methane Hydrate Formation in Confined Nanospace can Surpass Nature.Nature Communications, 6:6432. https://doi.org/10.1038/ncomms7432
Chen, F., Lu, H.F., Liu, J., et al., 2016.Sedimentary Geochemical Response to Gas Hydrate Episodic Release on the Northeastern Slope of the South China Sea.Earth Science, 41(10):1619-1629 (in Chinese with English abstract). https://doi.org/10.3799/dqkx.2016.120
Heeschen, K. U., 2017. Swapping Guests: Laborary Large-Scale Experiments on CH₄ Production by CO₂-CH₄ Exchange in a CH₄ Hydrate Reservoir. 9th International Conference on Gas Hydrate, Denver.
Kakuwa, Y., 2017. Occurrence of Shallow Gas Hydrate in the Eastern Margin of Japan Sea with a Discussion of a Supply System for Methane Gas. 9th International Conference on Gas Hydrate, Denver.
Knappitsch, F., 2017. Enhaned Methane Storage Capacity in Hierarchically Ordered Porous Media by Gas Hydrate Formation. 9th International Conference on Gas Hydrate, Denver.
Li, G., Wu, D.M., Li, X.S., et al., 2017.Experimental Investigation into the Production Behavior of Methane Hydrate under Methanol Injection in Quartz Sand.Energy Fuels, 31(5):5411-5418. https://doi.org/10.1021/acs.energyfuels.7b00464
Liu, H., Liu, B., Lin, L.C., et al., 2014.A Hybrid Absorption-Adsorption Method to Efficiently Capture Carbon.Nature Communications, 5:5147. https://doi.org/10.1038/ncomms6147
Matsumoto, R., 2017. Occurrence and Origin of Thick Deposits of Massive Gas Hydrate, Eastern Margin of the Sea of Japan. 9th International Conference on Gas Hydrate, Denver.
Pan, Y., Li, H., Zhang, X.X., et al., 2015.Large-Scale Synthesis of ZIF-67 and Highly Efficient Carbon Capture Using a ZIF-67/Glycol-2-Methylimidazole Slurry.Chemical Engineering Science, 137:504-514. doi: 10.1016/j.ces.2015.06.069
Pasieka, J., Jorge, L., Coulombe, S., et al., 2015.Effects of As-Produced and Amine-Functionalized Multi-Wall Carbon Nanotubes on Carbon Dioxide Hydrate Formation.Energy Fuels, 29(8):5259-5266. https://doi.org/10.1021/acs.energyfuels.5b01036
Schicks, J. M., 2017a. From Lab to Field, from Micro to Macro-Test of Technologies for the Production of Hydrate Bonded CH₄ via CO₂ Sequestration in Hydrates. 9th International Conference on Gas Hydrate, Denver.
Schicks, J. M., 2017b. From Micro to Macro: Experimental Investigations of the CO₂/N₂-CH₄ Exchange Process in Gas Hydrates under Conditions Similar to the Ignik Sikumi Field Trial in Different Scales. 9th International Conference on Gas Hydrate, Denver.
Sloan, E.D., Koh, C.A., 2008.Clathrate Hydrate of Natural Gases.Taylor & Fancis-CRC Press, London.
Su, M., 2017. Two Different Types of Fine-Grained Turbidities Associated with Gas Hydrates in the Shenhu Area, Nothern Continental Slope of the South China Sea. 9th International Conference on Gas Hydrate, Denver.
Su, Z., Cao, Y., Yang, R., et al., 2014.Research on the Formation Model of Gas Hydrate Deposits in the Shenhu Area, Northern South China Sea.Chinese Journal of Geophysics, 57(5):1664-1674. https://doi.org/10.6038/cjg20140529
Yu, H. Q., 2017. Ministry of Land and Resources, People's Government of Guangdong Province and China National Petroleum Corporation Signed "The Strategic Contract of Advancing Construction of Natural Gas Hydrates Test Exploration Area at Shenhu South China Sea". http://www.mlr.gov.cn/xwdt/jrxw/201708/t20170826_1578386.htm (in Chinese).
Zhang, X.X., Liu, H., Sun, C.Y., et al., 2014.Effect of Water Content on Separation of CO₂/CH₄ with Active Carbon by Adsorption-Hydration Hybrid Method.Separation and Purification Technology, 130:132-140. doi: 10.1016/j.seppur.2014.04.028
Zhang, X.X., Xiao, P., Zhan, C.H., et al., 2015.Separation of Methane/Ethylene Gas Mixtures Using Wet ZIF-8.Industrial & Engineering Chemistry Research, 54(32):7890-7898. https://doi.org/10.1021/acs.iecr.5b00941
Zhang, Y., Li, X.S., Wang, Y., et al., 2017.Methane Hydrate Formation in Marine Sediment from South China Sea with Different Water Saturations.Energies, 10(4):13. https://doi.org/10.3390/en10040561
Zhao, J.Z., Zhou, S.W., Zhang, L.H., et al., 2017.The First Global Physical Simulation Experimental Systems for the Exploitation of Marine Natural Gas Hydrates through Solid Fluidization.Natural Gas Industry, 37(9):15-22 (in Chinese with English abstract). https://doi.org/10.3787/j.issn.1000-0976.2017.09.002
Zheng, M.M., Jiang, G.S., Liu, T.L., et al., 2017.Physical Properties Response of Hydrate Bearing Sediments near Wellbore during Drilling Fluid Invasion.Earth Science, 42(3):453-461 (in Chinese with English abstract). https://doi.org/10.3799/dqkx.2017.035
Zhou, S.W., Zhao, J.Z., Li, Q.P., et al., 2017.Optimal Design of the Engineering Parameters for the First Global Trial Production of Marine Natural Gas Hydrates through Solid Fluidization.Natural Gas Industry, 37(9):1-14 (in Chinese with English abstract). https://doi.org/10.3787/j.issn.1000-0976.2017.09.001
陈芳, 陆红锋, 刘坚, 等, 2016.南海东北部陆坡天然气水合物多期次分解的沉积地球化学响应.地球科学, 41(10):1619-1629. http://www.earth-science.net/WebPage/Article.aspx?id=3367
于洪奇, 2017. 国土资源部、广东省人民政府、中国石油天然气集团公司签署《推进南海神狐海域天然气水合物勘查开采先导试验区建设战略合作协议》. http://www.mlr.gov.cn/xwdt/jrxw/201708/t20170826_1578386.htm
赵金洲, 周守为, 张烈辉, 等, 2017.世界首个海洋天然气水合物固态流化开采大型物理模拟实验系统.天然气工业, 37(9):15-22. doi: 10.3787/j.issn.1000-0976.2017.09.002
郑明明, 蒋国胜, 刘天乐, 等, 2017.钻井液侵入时水合物近井壁地层物性响应特征.地球科学, 42(3):453-461. https://www.researchgate.net/publication/269538254_haiditianranqishuihewudecengzuantanjiasuanyanzuanjingyeshiyan
周守为, 赵金洲, 李清平, 等, 2017.全球首次海洋天然气水合物固态流化试采工程参数优化设计.天然气工业, 37(9):1-14. doi: 10.3787/j.issn.1000-0976.2017.09.001