四川甲基卡新三号超大型锂矿脉稀土元素地球化学

刘丽君; 王登红; 代鸿章; 侯江龙

doi:10.3799/dqkx.2017.113

四川甲基卡新三号超大型锂矿脉稀土元素地球化学

doi: 10.3799/dqkx.2017.113

1.
中国地质大学地球科学与资源学院，北京100083
2.
中国地质科学院矿产资源研究所国土资源部成矿作用与资源评价重点实验室，北京100037

基金项目:

中国地质调查局项目 DD20160346

中国地质调查局项目 DD20160055

中国地质调查局项目 DD20160056

详细信息

作者简介:
刘丽君(1991-)，女，博士生，主要从事矿物学、岩石学、矿床学专业研究

通讯作者:
王登红

中图分类号: P618.71
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出版历程
- 收稿日期: 2017-04-18
- 刊出日期: 2017-10-18

Geochemical Characteristics of REE and Its Implications to X03 Super-Large Lithium Pegmatite Vein, Jiajika, Sichuan

1.
School of Earth Sciences and Resources, China University of Geosciences, Beijing100083, China
2.
MLR Key Laboratory of Metallogeny and Mineral Resource Assessment, Institute of Mineral Resources, Chinese Academy of Geological Sciences, Beijing100037, China

摘要

摘要: 四川甲基卡新三号(X03) 超大型锂矿脉是近年发现且价值巨大的锂矿化伟晶岩脉，但相对缺少地球化学的研究，利用ICP-MS测试手段对该矿脉ZK1101钻孔中44件样品进行分析测试，发现该矿脉稀土总量很低(∑REE为0.180×10^-6~8.613×10^-6，平均值为2.543×10^-6)，配分曲线呈右倾斜型，相对富集轻稀土，总体表现铕负异常.围岩的稀土含量与一般片岩相近(∑REE为160.134×10^-6~265.881×10^-6，平均值为230.718×10^-6)，稀土配分曲线总体呈右倾平滑趋势，富集轻稀土，铕为负异常.铕的分布具有特殊性，表现为铕在伟晶岩脉的边部具有显著的正异常.∑REE与Li呈负相关性，δCe与Li则表现为弱正相关性.这一首次发现的低稀土总量和矿脉边部Eu显著正异常的特殊性，对于甲基卡伟晶岩的含矿性评价可能具有重要意义.
- 甲基卡 /
- 新三号锂矿脉 /
- 稀土元素 /
- 铕异常 /
- 地球化学
Abstract: The super-large new No.3 (X03) lithium ore vein is a lithium mineralized pegmatite vein of great value. This paper summarizes the rare earth element (REE) geochemical characteristics by studying the typical drill ZK1101. Results show that the X03 lithium-mineralized pegmatite vein has a very low total amount of rare earth elements (∑REE =0.180×10^-6~8.613×10^-6, average=2.543×10^-6, n=24), the distribution curve is right-inclined type, which means the samples are enriched in LREE and depleted in HREE, and the pegmatite shows negative anomalies of Eu. The host rocks have general REE content (∑REE=160.134×10^-6~265.881×10^-6, average=230.718×10^-6, n=20). The rare earth distribution curve is generally inclined to the right, showing the enrichment of LREE and negative anomalies of Eu. The distribution of Eu in rare earth elements is specific, and Eu has a strong positive anomaly at the edge of the pegmatite vein. ∑REE is negatively correlated with Li, δCe and Li show a slight positive correlation, revealing the inverse correlation between rare earth element and lithium. It also means that the low content of REE is an important prospecting sign for rare metals mineralized pegmatites.
- Jiajika /
- X03 lithium mineralized vein /
- rare earth element /
- Eu anomaly /
- geochemistry

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图 1 川西甲基卡矿田地质简图

据唐国凡和吴盛先(1984)修改.1.二云母花岗岩；2.微斜长石型伟晶岩；3.微斜长石-钠长石型伟晶岩；4.钠长石型伟晶岩；5.钠长石-锂辉石型伟晶岩；6.钠长石-锂云母型伟晶岩；7.新发现矿脉及编号；8.伟晶岩类型分带线；9.伟晶岩类型；10.伟晶岩脉编号.Ⅰ.微斜长石伟晶岩带；Ⅱ.微斜长石-钠长石伟晶岩带；Ⅲ.钠长石伟晶岩带；Ⅳ.锂辉石伟晶岩带；Ⅴ.锂(白)云母伟晶岩带

Fig. 1. Geological map of the Jiajika ore field in western Sichuan Province

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图 2 甲基卡新三号脉平面地质简图(a)和剖面地质简图(b)

据付小方等(2015)和刘丽君等(2016)修改.新三号矿脉实际未出露地表；a.矿体水平投影图.1.第四系坡积物；2.上三叠统西康群砂页岩；3.矿体及编号；4.地质界线；5.推测矿体界线；6.剖面线；7.图a钻孔及编号；8.图b钻孔及深度

Fig. 2. Simplified geological map (a) and profile (b) of X03 Li-bearing vein in the Jiajika field

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图 3 甲基卡新三号矿脉伟晶岩及围岩的典型镜下照片

矿物代号参照国家标准《区域地质图图例GB958-2015》；a.矿脉中部的含锂辉石矿石；b.矿脉接触带的含锂辉石矿石；c.远离矿脉的围岩；d.靠近接触带的围岩，电气石化蚀变；Alm.铁铝榴石；Ab.钠长石；Bi.黑云母；Mic.微斜长石；Mu.白云母；Qz.石英；Spo.锂辉石；St.十字石；Tou.电气石

Fig. 3. Pictures of pegmatite and host rock of X03 Li-bearing vein

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图 4 甲基卡新三号锂矿脉ZK1101Li含量及稀土参数垂向分布

标准值引自Taylor and McLennan, 1985

Fig. 4. Vertical distribution of Li content and REE parameters from ZK1101, X03 Li-bearing vein, Jiajika

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图 5 甲基卡矿区新三号锂矿脉稀土元素配分曲线对比

标准化值引自Taylor and McLennan, 1985.a.甲基卡新三号锂矿脉矿石；b.甲基卡新三号锂矿脉接触带矿石；c.甲基卡新三号锂矿脉上矿层矿石；d.甲基卡新三号锂矿脉下矿层矿石；e.甲基卡新三号锂矿脉围岩；f.甲基卡矿区各类岩石对比

Fig. 5. REE distribution of X03 Li-bearing vein and host rocks in Jiajika

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图 6 伟晶岩脉稀土元素配分对比

Fig. 6. REE distribution of different pegmatite veins

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图 7 新三号锂矿脉中矿石的δEu值与其距离矿层中心点位置的相关性图解

Fig. 7. Relativity diagram of δEu and distance of ores to the center of each ore layer from ZK1101, X03 Li-bearing vein, Jiajika pegmatite ore field

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图 8 甲基卡新三号锂矿脉Li与稀土参数相关性图解

Fig. 8. Relativity diagram of REE parameter and Li content from ZK1101, X03 Vein, Jiajika

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表 1 甲基卡X03号锂矿脉ZK1101围岩样品锂及稀土含量(10^-6)

Table 1. REE and Li contents (10^-6) of host rock samples from ZK1101, X03 Li-vein, Jiajika pegmatite field

样品原号	位置	Li	La	Ce	Pr	Nd	Sm	Eu	Gd	Tb	Dy	Ho	Er	Tm	Yb	Lu	Y	∑REE	LREE/ HREE	δEu	δCe	La/Yb	Sm/Nd
JJK1101-12.6	接触带	2212	39.842	83.217	9.404	38.070	7.958	1.513	7.996	1.094	6.014	1.209	3.975	0.490	3.576	0.511	29.053	233.922	7.239	0.574	0.981	11.140	0.209
JJK1101-43.5	接触带	1272	41.451	82.047	9.712	38.420	7.980	1.742	8.399	1.035	6.296	1.182	3.887	0.499	3.500	0.516	31.232	237.898	7.164	0.646	0.933	11.842	0.208
JJK1101-43.9	接触带	1195	42.791	86.450	10.035	37.742	8.294	1.660	8.655	0.984	5.907	1.105	3.703	0.491	3.320	0.509	28.675	240.320	7.578	0.595	0.952	12.891	0.220
JJK1101-49.27	围岩1	574	42.320	85.643	10.111	37.351	8.169	1.777	8.313	1.015	6.076	1.157	3.882	0.479	3.481	0.516	31.933	242.223	7.439	0.653	0.946	12.158	0.219
JJK1101-50.9	围岩1	611	27.956	57.230	6.379	24.779	5.395	1.124	5.397	0.728	4.227	0.803	2.541	0.318	2.273	0.328	20.838	160.315	7.394	0.631	0.974	12.301	0.218
JJK1101-56.6	围岩1	710	44.973	91.687	10.798	40.366	8.974	1.822	8.617	1.028	5.978	1.155	3.774	0.489	3.340	0.522	30.164	253.686	7.976	0.625	0.952	13.466	0.222
JJK1101-64.05	围岩1	626	44.874	91.454	10.395	38.921	8.327	1.596	8.546	1.022	6.025	1.215	3.950	0.532	3.775	0.593	31.307	252.531	7.622	0.574	0.965	11.888	0.214
JJK1101-69.2	接触带	913	43.039	86.391	9.776	38.173	7.675	1.642	8.512	0.959	5.707	1.073	3.616	0.457	3.130	0.478	27.912	238.541	7.801	0.618	0.957	13.749	0.201
JJK1101-69.7	接触带	2645	46.338	92.824	10.549	38.698	8.112	1.186	8.382	1.049	5.891	1.178	3.975	0.492	3.378	0.506	29.254	251.812	7.956	0.436	0.954	13.718	0.210
JJK1101-80	接触带	825	34.683	69.748	7.633	30.605	6.052	1.224	6.596	0.796	4.421	0.821	2.867	0.351	2.446	0.367	21.714	190.324	8.034	0.589	0.970	14.180	0.198
JJK1101-80.1	接触带	826	28.263	57.589	6.595	25.046	5.477	1.119	5.621	0.705	4.126	0.772	2.441	0.330	2.304	0.361	19.384	160.134	7.448	0.611	0.962	12.269	0.219
JJK1101-85.7	围岩2	464	43.776	107.241	9.566	37.965	6.848	1.363	7.484	0.844	4.905	1.050	3.832	0.511	3.737	0.564	26.806	256.494	9.018	0.579	1.185	11.713	0.180
JJK1101-86	围岩2	583	41.538	83.104	9.277	36.593	7.542	1.614	7.897	0.990	5.631	1.078	3.596	0.458	3.081	0.477	28.811	231.687	7.742	0.635	0.960	13.480	0.206
JJK1101-86.9	围岩2	580	43.956	92.685	10.439	38.070	8.044	1.669	8.143	1.009	6.182	1.172	4.016	0.515	3.716	0.546	29.873	250.037	7.702	0.625	0.988	11.828	0.211
JJK1101-107	围岩2	32	39.643	93.341	8.526	33.097	6.740	1.056	6.844	0.795	4.435	0.762	2.487	0.313	2.348	0.378	20.513	221.280	9.933	0.471	1.146	16.882	0.204
JJK1101-107.13	围岩2	158	39.036	78.109	9.208	35.189	7.240	1.637	7.390	0.932	5.371	1.028	3.503	0.416	2.954	0.467	26.702	219.181	7.725	0.678	0.940	13.216	0.206
JJK1101-110.77	围岩2	295	44.779	88.136	10.615	41.753	8.219	1.522	7.627	1.005	6.083	1.173	4.139	0.520	3.679	0.533	30.248	250.035	7.877	0.578	0.923	12.171	0.197
JJK1101-111.07	围岩2	195	37.845	80.529	9.110	34.541	7.219	1.714	7.674	0.937	5.300	1.041	3.453	0.468	3.055	0.489	25.718	219.094	7.626	0.700	0.992	12.390	0.209
JJK1101-118.54	围岩2	382	48.142	98.388	10.772	42.736	8.796	1.976	8.526	1.079	6.226	1.130	3.917	0.489	3.692	0.539	29.473	265.881	8.236	0.689	0.980	13.038	0.206
JJK1101-125.6	围岩2	1171	43.260	87.495	9.895	37.508	8.369	1.726	8.235	1.057	5.705	1.055	3.588	0.462	3.269	0.459	26.885	238.968	7.900	0.629	0.962	13.234	0.223

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表 2 甲基卡X03号锂矿脉矿石样品锂及稀土含量(10^-6)

Table 2. REE and Li contents (10^-6) of drill ores from ZK1101, X03 Li-vein, Jiajika pegmatite field

样品原号	位置	Li	La	Ce	Pr	Nd	Sm	Eu	Gd	Tb	Dy	Ho	Er	Tm	Yb	Lu	Y	∑REE	LREE/ HREE	δEu	δCe	La/Yb	Sm/Nd
JJK1101-2.3	上矿层1	16 880	0.459	0.845	0.054	0.128	0.047	0.005	0.073	0.021	0.082	0.005	0.016	0.002	0.013	0.001	0.422	2.173	7.206	0.248	1.075	34.646	0.365
JJK1101-5.6	上矿层1	17 970	0.146	0.266	0.017	0.076	0.016	0.002	0.027	0.005	0.023	0.003	0.007	0.001	0.012	0.001	0.118	0.721	6.631	0.274	1.065	12.144	0.206
JJK1101-7.7	上矿层1	540	1.275	2.242	0.260	0.900	0.374	0.018	0.519	0.100	0.496	0.048	0.122	0.012	0.113	0.013	2.120	8.613	3.564	0.126	0.872	11.266	0.415
JJK1101-9.4	上矿层1	9 878	0.185	0.207	0.014	0.028	0.013	0.004	0.019	0.003	0.014	0.004	0.005	0.000	0.007	0.000	0.094	0.596	8.474	0.757	0.716	24.827	0.472
JJK1101-12.3	接触带	7 100	0.887	1.650	0.159	0.603	0.229	0.117	0.167	0.036	0.207	0.028	0.089	0.013	0.086	0.013	1.022	5.307	5.700	1.745	0.963	10.324	0.380
JJK1101-12.8	接触带	7 217	0.907	1.656	0.168	0.568	0.370	0.564	0.230	0.046	0.218	0.036	0.109	0.018	0.162	0.023	1.367	6.442	5.030	5.506	0.935	5.611	0.652
JJK1101-17.2	上矿层2	9 386	0.700	1.180	0.100	0.241	0.107	0.010	0.133	0.033	0.131	0.017	0.038	0.006	0.038	0.006	0.790	3.530	5.813	0.265	0.936	18.599	0.442
JJK1101-21.3	上矿层2	13 560	0.615	1.121	0.084	0.205	0.084	0.003	0.128	0.032	0.118	0.013	0.018	0.004	0.010	0.002	0.530	2.967	6.492	0.088	1.023	64.001	0.410
JJK1101-22.9	上矿层2	10 510	0.827	1.100	0.080	0.203	0.069	0.000	0.090	0.013	0.048	0.004	0.010	0.002	0.007	0.001	0.253	2.705	13.098	0.000	0.810	125.451	0.339
JJK1101-23.72	上矿层2	15 130	0.245	0.381	0.028	0.086	0.028	0.000	0.048	0.011	0.049	0.004	0.011	0.000	0.005	0.002	0.233	1.130	5.963	0.000	0.912	49.576	0.324
JJK1101-26.3	上矿层2	8 202	0.239	0.395	0.026	0.057	0.036	0.002	0.050	0.013	0.058	0.006	0.007	0.001	0.010	0.002	0.243	1.145	5.128	0.180	0.983	23.554	0.633
JJK1101-30	上矿层2	5 347	0.778	1.277	0.088	0.151	0.071	0.003	0.103	0.031	0.142	0.011	0.014	0.003	0.022	0.003	0.589	3.286	7.185	0.105	0.966	35.135	0.474
JJK1101-32.85	上矿层2	14 060	0.209	0.327	0.029	0.088	0.033	0.001	0.033	0.007	0.034	0.003	0.003	0.001	0.004	0.001	0.109	0.883	7.936	0.060	0.872	47.562	0.379
JJK1101-35.6	上矿层2	17 330	0.029	0.068	0.003	0.010	0.005	0.003	0.006	0.001	0.008	0.001	0.002	0.001	0.001	0.000	0.042	0.180	5.832	1.427	1.410	56.516	0.540
JJK1101-36.8	上矿层2	9 763	0.130	0.233	0.016	0.031	0.017	0.001	0.020	0.010	0.040	0.003	0.011	0.002	0.004	0.001	0.184	0.704	4.760	0.117	1.028	36.505	0.556
JJK1101-37.93	上矿层2	13 190	0.377	0.555	0.046	0.089	0.053	0.002	0.081	0.023	0.070	0.006	0.009	0.001	0.008	0.001	0.342	1.664	5.620	0.094	0.851	44.790	0.596
JJK1101-41.74	上矿层2	9 525	0.126	0.234	0.013	0.051	0.016	0.000	0.019	0.005	0.032	0.004	0.007	0.001	0.012	0.001	0.181	0.702	5.455	0.000	1.113	10.170	0.312
JJK1101-42.97	接触带	259	0.358	0.547	0.060	0.239	0.219	0.292	0.118	0.019	0.089	0.015	0.061	0.009	0.053	0.007	0.544	2.629	4.634	5.026	0.810	6.804	0.918
JJK1101-69.8	接触带	274	1.361	2.466	0.213	0.751	0.217	0.134	0.248	0.035	0.211	0.032	0.084	0.014	0.080	0.012	0.973	6.831	7.189	1.759	0.978	17.048	0.289
JJK1101-70.50	下矿层	217	0.451	0.706	0.054	0.151	0.044	0.007	0.054	0.012	0.048	0.003	0.009	0.002	0.011	0.001	0.192	1.746	10.086	0.465	0.910	40.390	0.292
JJK1101-70.95	下矿层	9 523	0.074	0.095	0.009	0.021	0.008	0.001	0.009	0.003	0.006	0.001	0.002	0.001	0.008	0.001	0.051	0.290	6.745	0.484	0.750	8.767	0.401
JJK1101-75.75	下矿层	13 990	0.445	0.650	0.062	0.127	0.049	0.006	0.086	0.021	0.104	0.008	0.015	0.001	0.014	0.001	0.430	2.018	5.351	0.257	0.816	31.404	0.390
JJK1101-77.3	下矿层	13 260	0.163	0.367	0.027	0.052	0.045	0.000	0.064	0.014	0.071	0.005	0.010	0.001	0.009	0.000	0.283	1.113	3.732	0.000	1.195	17.547	0.872
JJK1101-79.4	下矿层	7 512	0.727	1.318	0.123	0.482	0.108	0.026	0.134	0.023	0.105	0.014	0.028	0.006	0.029	0.004	0.531	3.659	8.118	0.664	0.956	25.090	0.223

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表 3 甲基卡矿区及不同伟晶岩脉稀土元素含量(10^-6)

Table 3. REE contents (10^-6) of Jiajika X03 pegmatite vein and other rare mineralization pegmatite veins

位置	岩性	La	Ce	Pr	Nd	Sm	Eu	Gd	Tb	Dy	Ho	Er	Tm	Yb	Lu	Y	∑REE	原始数据来源
四川甲基卡X03号脉ZK1101	内部伟晶岩矿石，n=20	0.410	0.678	0.057	0.159	0.061	0.005	0.085	0.019	0.084	0.008	0.017	0.002	0.017	0.002	0.387	1.991	本文
四川甲基卡X03号脉ZK1101	接触带部伟晶岩矿石，n=4	0.878	1.580	0.150	0.540	0.259	0.277	0.191	0.034	0.181	0.028	0.086	0.013	0.095	0.014	0.977	5.302	本文
四川甲基卡X03号脉ZK1101	伟晶岩矿石总，n=24	0.488	0.829	0.072	0.222	0.094	0.050	0.102	0.022	0.100	0.011	0.029	0.004	0.030	0.004	0.485	2.543	本文
四川甲基卡X03号脉ZK1101	围岩，n=20	40.925	84.665	9.440	36.281	7.572	1.534	7.743	0.953	5.525	1.058	3.557	0.454	3.203	0.483	27.325	230.718	本文
四川甲基卡	二云母花岗岩平均值，n=4	6.030	10.233	1.423	7.378	1.570	0.290	1.695	0.283	1.355	0.185	0.390	0.043	0.245	0.033	-	31.150	梁斌等，2016
福建南平31号脉	白云母钠长石锂辉石伟晶岩	1.200	1.300	0.180	0.970	0.150	0.040	0.190	0.030	0.210	0.040	0.090	0.020	0.100	0.010	1.370	5.900	杨岳清等，1988
新疆可可托海	冷凝边	0.940	3.280	0.300	1.270	0.210	0.060	0.220	0.040	0.210	0.040	0.100	0.020	0.120	0.020	0.870	7.700	冷成彪等，2007
新疆可可托海	细粒钠长石岩	0.590	1.470	0.140	0.260	0.070	0.010	0.130	0.020	0.090	0.020	0.060	0.010	0.100	0.010	0.300	3.280	冷成彪等，2007
新疆可可托海	薄片状钠长石岩	0.650	1.210	0.130	0.350	0.100	0.010	0.090	0.010	0.030	0.010	0.030	0.010	0.040	0.010	0.120	2.800	冷成彪等，2007
青海沙流泉	电气石化花岗伟晶岩	0.800	1.690	0.230	0.870	0.440	0.050	0.520	0.070	0.280	0.050	0.100	0.050	0.170	0.050	1.560	6.930	李善平等，2016
青海沙流泉	云英岩化花岗伟晶岩	2.600	5.240	0.940	3.360	2.210	0.050	2.380	0.520	2.360	0.260	0.670	0.120	1.170	0.200	13.600	35.680	李善平等，2016
注：n代表样品数量；-代表无数据.

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参考文献(41)

Chen, D.Q., Chen, G., 1990.Practical Rare Earth Element Geochemistry.Metallurgical Industry Press, Beijing (in Chinese).
Fu, X.F., Yuan, L.P., Wang, D.H., et al., 2015.Mineralization Characteristics and Prospecting Model of Newly Discovered X03 Rare Metal Vein in Jiajika Orefield, Sichuan.Mineral Deposits, 24(6):1172-1186 (in Chinese with English abstract).doi: 10.16111/j.0258-7106.2015.06.006
Hao, X.F., Fu, X.F., Liang, B., et al., 2015.Formation Ages of Granite and X03 Pegmatite Vein in Jiajika, Western Sichuan, and Their Geological Significance.Mineral Deposits, 34(6):1199-1208.doi: 10.16111/j.0258-7106.2015.06.008
Lan, X.H., Li, R.H., Mi, B.B., et al., 2016.Distribution Characteristics of Rare Earth Elements in Surface Sediment and Their Provenance Discrimination in the Eastern Bohai and Northern Yellow Seas.Earth Science, 41(3):463-474. doi: 10.1007/s12665-015-4391-x
Leng, C.B., Wang, S.X., Gou, T.Z., et al., 2007.A Review of the Research on the Kokotokay No.3 Granitic Pegmatite Dyke, Altai, Xinjiang.Geology and Mineral Resources of South China, 1:14-20 (in Chinese with English abstract).
Li, C.N., 1992.Trace Element Petrology of Igneous Rock.China University of Geosciences Press, Wuhan (in Chinese).
Li, S.P., Zhao S.Z., Jin, T.T., et al., 2016.REE Geochemical Characteristics and Provenance Analysis of the Shaliuquan Niobium Tantalum Pegmatite Ore, Qinghai Province.Chinese Rare Earths, 37(1):39-46 (in Chinese with English abstract). http://www.academia.edu/23719887/Tectonic_and_Structural_Characteristics_of_Iron_Deposits_in_Attepe_and_Its_Vicinity_Kayseri-Adana_Basin_Turkey_
Liang, B., Fu, X.F., Tang, Y., et al., 2016.Granite Geochemical Characteristics in Jiajika Rare Metal Deposit, Western Sichuan.Journal of Guilin University of Technology, 36(2):42-49 (in Chinese with English abstract).doi: 10.3969/j.issn.1674-9057.2016.01.007
Liu, L.J., Fu, X.F., Wang, D.H., et al., 2015.Geological Characteristics and Metallogeny of Jiajika-Style Rare Metal Deposts.Mineral Deposits, 34(6):1187-1198 (in Chinese with English abstract).doi: 10.16111/j.0258-7106.2015.06.007
Liu, L.J., Wang, D.H., Hou, K.J., et al., 2017.Application of Lithium Isotope to Jiajika New No.3 Pegmatite Lithium Polymetallic Vein in Sichuan.Earth Science Frontiers, 24(5):167-171 (in Chinese with English abstract).doi: 10.13745/j.esf.yx.2017-1-16
Liu, L.J., Wang, D.H., Yang, Y.Q., et al., 2016.Metallogenic Characteristics of X03 Rare Metal Vein in Jiajika of Sichuan.Journal of Guilin University of Technology, 36(2):42-49 (in Chinese with English abstract).doi: 10.3969/j.issn.1674-9057.2016.01.008
Liu, Y.J., Cao, L.M., Li, Z.L., et al., 1984.Elemental Geochemistry.Science Press, Beijing (in Chinese).
Mineralogist, A., Aur-R, R., 1975.Mineralogy and Rare Earth Geochemistry of Apatite and Xenotime from the Gloserheia Granite Pegmatite, Froland, Southern Norway.American Mineralogist, 60:607-620. doi: 10.1007/978-3-642-87262-4_1
Ren, J.B., He, G.W., Yao, H.Q., et al., 2016.Geochemistry and Significance of REE and PEG of the Cobalt-Rich from West Pacific Ocean Seamounts.Earth Science, 41(10):1745-1757. http://www.academia.edu/7144356/Geochemistry_of_Paleocene-Eocene_limestones_from_Ching-dar_syncline_west_of_Birjand_east_of_Iran
Pan, M., Tang, Y., Xiao, R.Q., et al., 2016.The Discovery of the Superlarge Li Ore Vein X03 in the Jiajika Ore District.Acta Geologica Sichuan, 36(3):422-425, 430 (in Chinese with English abstract).doi: 10.3969/j.issn.1006-0995.2016.03.016
Tang, G.F., Wu, S.X., 1984.Geological Research Report on Jiajika Granitic Pegmatite Lithium Deposit in Kangding, Sichuan.Beijing, Geological Publishing House (in Chinese).
Taylor, S.R., McLennan, S.M., 1985.The Continental Crust:Its Composition and Evolution.Blackwell, Oxford, 57-114.
Taylor, B.E., Slack, J.F., 1984.Tourmalines from Appalachian-Caledonian Massive Sulfide Deposits; Textural, Chemical, and Isotopic Relationships.Economic Geology, 79(7):1703-1726. doi: 10.2113/gsecongeo.79.7.1703
Wang, D.H., Fu, X.F., 2013.Breakthrough of Lithium Prospecting on the Periphery of Jiajika, Sichaun.Rock and Mineral Analysis, 32(6):987-987 (in Chinese).doi: 10.15898/j.cnki.11-2131/td.2013.06.019
Wang, D.H., Wang, R.J., Fu, X.F., et al., 2016.A Discussion on the Major Problems Related to Geological Investigation and Assessment for Energy Metal Resources Base:A Case Study of the Jiajika Large Lithium Mineral Resource Base.Acta Geoscientica Sinica, 37(4):471-480 (in Chinese with English abstract).doi: 10.3975/cagsb.2016.04.09
Wang, D.H., Liu, L.J., Hou, J.L., et al., 2017.A Prime Review on Application of"Five Levels+Basement"Model for Jiajika-Style Rare Metal Deposits.Earth Science Frontiers, 24(5):1-7 (in Chinese with English abstract).doi: 10.13745/j.esf.yx.2017-1-1
Yang, Y.Q., Guo, Y.Q., Qiu, N.M., et al., 1988.The REE Geochemistry of the Nanping Granitic Pegamtite Ore Field in Fujian Province.Geological Publishing House, Beijing, 69-83 (in Chinese).
陈德潜, 陈刚, 1990.实用稀土元素地球化学.北京:冶金工业出版社.
付小方, 袁蔺平, 王登红, 等, 2015.四川甲基卡矿田新三号稀有金属矿脉的成矿特征与勘查模型.矿床地质, 24(6): 1172-1186. http://www.cnki.com.cn/Article/CJFDTOTAL-KCDZ201506007.htm
郝雪峰, 付小方, 梁斌, 等, 2015.川西甲基卡花岗岩和新三号矿脉的形成时代及意义.矿床地质, 34(6): 1199-1208. http://www.cnki.com.cn/Article/CJFDTOTAL-KCDZ201506009.htm
蓝先洪, 李日辉, 密蓓蓓, 等, 2016.渤海东部和黄海北部表层沉积物稀土元素的分布特征与物源判别.地球科学, 41(3): 463-474. http://earth-science.net/WebPage/Article.aspx?id=3272
冷成彪, 王守旭, 苟体忠, 等, 2007.新疆阿尔泰可可托海3号伟晶岩脉研究.华南地质与矿产, 1: 14-20. doi: 10.3969/j.issn.1007-3701.2007.01.003
李昌年, 1992.火成岩微量元素岩石学.武汉:中国地质大学出版社.
李善平, 湛守智, 金婷婷, 等, 2016.青海沙流泉铌钽矿床伟晶岩稀土元素地球化学特征及物源分析.稀土, 37(1): 39-46. http://www.cnki.com.cn/Article/CJFDTOTAL-XTZZ201601008.htm
梁斌, 付小方, 唐屹, 等, 2016.川西甲基卡稀有金属矿区花岗岩岩石地球化学特征.桂林理工大学学报, 36(2): 42-49. http://www.cnki.com.cn/Article/CJFDTOTAL-GLGX201601007.htm
刘丽君, 付小方, 王登红, 等, 2015.甲基卡式稀有金属矿床的地质特征与成矿规律.矿床地质, 34(6): 1187-1198. http://www.cnki.com.cn/Article/CJFDTOTAL-KCDZ201506008.htm
刘丽君, 王登红, 侯可军, 等, 2017.锂同位素在四川甲基卡新三号矿脉研究中的应用.地学前缘, 24(5): 167-171. http://www.cnki.com.cn/Article/CJFDTOTAL-DXQY201705021.htm
刘丽君, 王登红, 杨岳清, 等, 2016.四川甲基卡新三号稀有金属矿脉成矿特征的初步研究.桂林理工大学学报, 36(1): 50-59. http://www.cnki.com.cn/Article/CJFDTOTAL-GLGX201601008.htm
刘英俊, 曹励明, 李兆麟, 等, 1984.元素地球化学.北京:科学出版社.
潘蒙, 唐屹, 肖瑞卿, 等, 2016.甲基卡新3号超大型锂矿脉找矿方法.四川地质学报, 36(3): 422-425, 430. http://www.cnki.com.cn/Article/CJFDTOTAL-SCDB201603016.htm
任江波, 何高文, 姚会强, 等, 2016.西太平洋海山富钴结壳的稀土和铂族元素特征及其意义.地球科学, 41(10): 1745-1757. http://earth-science.net/WebPage/Article.aspx?id=3376
唐国凡, 吴盛先, 1984.四川省康定县甲基卡花岗伟晶岩锂矿床地质研究报告.北京:地质出版社.
王登红, 付小方, 2013.四川甲基卡外围锂矿找矿取得突破.岩矿测试, 32(6): 987-987. http://www.cnki.com.cn/Article/CJFDTOTAL-YKCS201306031.htm
王登红, 王瑞江, 付小方, 等, 2016.对能源金属矿产资源基地调查评价基本问题的探讨——以四川甲基卡大型锂矿基地为例.地球学报, 37(4): 471-480. http://www.cnki.com.cn/Article/CJFDTOTAL-DQXB201604012.htm
王登红, 刘丽君, 侯江龙, 等.2017.初论甲基卡式稀有金属矿床"五层楼+地下室"勘查模型.地学前缘, 24(5): 1-7. http://www.cnki.com.cn/Article/CJFDTOTAL-DXQY201705002.htm
杨岳清, 郭永泉, 仇年铭, 等, 1988.福建南平花岗伟晶岩矿田中稀土元素地球化学.北京:地质出版社, 69-83.