莺歌海盆地黄流组浅海重力流砂体物源分析及油气地质意义

黄银涛; 姚光庆; 周锋德

doi:10.3799/dqkx.2016.511

莺歌海盆地黄流组浅海重力流砂体物源分析及油气地质意义

doi: 10.3799/dqkx.2016.511

黄银涛^1,2,,
姚光庆^1,2, ,,
周锋德^1,2

1.
中国地质大学构造与油气资源教育部重点实验室，湖北武汉 430074
2.
中国地质大学资源学院，湖北武汉 430074

基金项目:

中海石油有限公司湛江分公司资助项目 CCL-2013-ZJFN1012

详细信息

作者简介:
黄银涛(1989-)，男，博士研究生，主要从事油气储层地质研究工作. E-mail: huangyintao@hotmail.com

通讯作者:
姚光庆, E-mail: gqyao@cug.edu.cn

中图分类号: P595
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出版历程
- 收稿日期: 2016-01-16
- 刊出日期: 2016-09-15

Provenance Analysis and Petroleum Geological Significance of Shallow-Marine Gravity Flow Sandstone for Huangliu Formation of Dongfang Area in Yinggehai Basin, the South China Sea

Huang Yintao^{1,2
,},
Yao Guangqing^{1,2
, ,},
Zhou Fengde^1,2

1.
Key Laboratory of Tectonics and Petroleum Resources of Ministry of Education, China University of Geosciences, Wuhan 430074, China
2.
Faculty of Earth Resources, China University of Geosciences, Wuhan 430074, China

摘要

摘要: 莺歌海盆地中央带上中新统黄流组一段近年新发现一套浅海重力流沉积体系，夹持于海南古隆起和越南昆嵩古隆起之间，探讨其物源供给对掌握砂体展布规律以及“源－汇复合体系”的研究具有重要意义.结合东方气田新钻井资料和岩石测试资料，如砂岩碎屑组分、重矿物组合特征及元素地球化学特征对研究区黄流组物源进行了分析, 结果表明：(1) 西部昆嵩隆起物源是本区浅海重力流沉积体系的主要物源区，浅海重力流砂岩长石、岩屑含量较高，结构成熟度高，泥质含量低(平均3.8%)，以岩屑石英细－极细砂岩为主；源自东部物源浅海砂坝砂岩的长石、岩屑含量较低，成分成熟度高，但泥质含量高(平均18.6%)，以岩屑石英粉砂岩－石英粉砂岩为主；(2) 源于西部物源的浅海重力流砂岩锆石、电气石含量低，磁铁矿、石榴石含量高，源于东部物源的浅海砂坝锆石、电气石、白钛矿含量高，磁铁矿、石榴石含量低.此外，区域古水流方向主要为南东－东西向，反映其可能受到西部越南水系的影响；(3) 岩心样品相似的稀土元素配分模式表明浅海重力流砂岩具有一致的物质来源，稀土元素含量及比值、Th-Sc及Co/Th-La/Sc图解均显示中性－长英质源岩特征，La-Th-Sc三角图、Th-Sc-Zr/10三角图以及主量元素判别图解均显示样品落在主动大陆边缘或大陆岛弧区域，说明浅海重力流砂岩源区为挤压构造背景，与昆嵩隆起相符合；(4) 中央底辟带西侧的浅海重力流砂体规模大，物性好，含气丰富，为下一步向西部勘探的主力砂体，而中央底辟带东侧的浅海砂坝储层规模较小，储层质量较差.
- 物源分析 /
- 浅海重力流 /
- 黄流组 /
- 莺歌海盆地 /
- 地球化学 /
- 油气
Abstract: The reservoir in Upper Miocene Huangliu Formation of Yinggehai basin, which is located between Kuntum paleo-uplift and Hainan paleo-uplift, is shallow-marine gravity flow deposits with burial depth ranging from 2 600 to 3 500 m. Analyzing the provenance of the sandbody is significant in understanding its distribution and "source to sink system", hence for the oil-gas exploration and development in this area. The provenance of sediments in Upper Miocene Huangliu Formation was analyzed by integrating the components of the sandstones, assemblage styles of the heavy mineral, paleo-current direction and geochemistry characteristics of the sandstones. Results show follows. (1) There are two provenances, one from west and the other from east, in the study area. Western sourced sandstones form the shallow-marine gravity flow which are mainly sublitharenite with high feldspar (average is 6.1%) and lithic (average is 11.7%) contents, low shale content (average is 3.8%). However, eastern sourced sandstones, which are mainly subarkose-quartz siltstone with low feldspar and lithic contents with averages of 4.6% and 2.7%, respectively, high compositional maturity, high shale contents (average is 18.6%), form the neritic sand bar. (2) The shallow-marine gravity flow sandstones exhibit low zircon, tourmaline contents, and high magnetite, garnet contents, while the neritic sand bar sandstones exhibit high zircon, tourmaline and leucosphenite contents, and low magnetite, garnet contents. The direction of paleo-current in study area is from southeastward to eastward. (3) The similar rare earth element (REE) patterns of 28 sandstones from three western wells indicate that they were sourced from the same provenance. The diagrams of Th-Sc and Co/Th-La/Sc and elemental ratios of these sandstone samples show that they were derived from intermediate to felsic source rocks. The measured geochemistry data of these core samples fall into the fields of active continental margin or continental island arc in the diagrams of La-Th-Sc, Th-Sc-Zr/10, Ti/Zr-La/Sc and major element discrimination, indicating that the source rocks of the shallow-marine gravity flow sandstones were formed under the tectonic setting of an convergent environment. (4) The integrated method for provenance analysis indicates that the shallow-marine gravity flow sandstones were derived from the western Kuntum uplift. The shallow-marine gravity flow sandstones in western mud diaper belts are large in scale, rich in gas, better in reservoir properties and the main favorable exploration target towards the west, whereas the neritic sand bar sandstones in eastern mud diaper belts are small in scale, poor in reservoir quality.
- provenance /
- shallow-marine gravity flow /
- Huangliu Formation /
- geochemistry /
- hydrocarbon /

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图 1 莺歌海盆地研究区位置(a)、地层系统(b)、井位及沉积体系分布(c)及过研究区地震剖面(d)

图 1a~1c据张伙兰(2013)修改

Fig. 1. Location of the study area (a), stratum system (b), location of wells and distribution of sedimentary systems (c), and one seismic section from the study area (d) in Yingehai basin

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图 2 砂岩元素地化样品分布

Fig. 2. The locations of sandstone samples which were collected for geochemistry analysis

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图 3 黄流组一段砂岩组分三角图

Fig. 3. The QFL triangle diagram of sandstones from member #1 of Huangliu Formation

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图 4 黄流组一段重矿物组合平面分布

Fig. 4. The distribution of heavy mineral assemblages from member #1 of Huangliu Formation

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图 5 黄流组一段古水流平面分布

Fig. 5. The distribution of paleo-current from member #1 of Huangliu Formation

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图 6 黄流组砂岩稀土元素配分模式

球粒陨石、UCC及PAAS数据来自于Henderson(1984)、Taylor and McLennan(1985)及Rudnick and Gao(2003)

Fig. 6. The REE pattern of the sandstone samples from Huangliu Formation

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图 7 黄流组砂岩Th-Sc(a)及Co/Th-La/Sc(b)图解

Th/Sc=1代表平均大陆上地壳，据Taylor and McLennan(1985)

Fig. 7. Th-Sc (a) and Co/Th-La/Sc (b) diagram of sandstones from Huangliu Formation

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图 8 黄流组砂岩La-Th-Sc(a)、Th-Sc-Zr/10(b)和黄流组砂岩主量元素(DF1-DF2) 判别图解(c)

OIA.大洋岛弧；CIA.大陆岛弧；ACM.主动大陆边缘；PM.被动大陆边缘

Fig. 8. La-Th-Sc (a), Th-Sc-Zr/10 (b) and discriminant function diagram for the tectonic setting using major elements (c) of Huangliusha Formation

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表 1 莺歌海盆地东方区岩石成分

Table 1. The proportion of sandstone components of study area

微相	井号	气组	厚度(m)	面孔率(%)	粒度中值(μm)	胶结物含量(%)	碎屑组分(%)			结构成熟度		成分成熟度		排替压力(MPa)	中值压力(MPa)	平均孔喉半径(μm)	岩石类型
微相	井号	气组	厚度(m)	面孔率(%)	粒度中值(μm)	胶结物含量(%)	石英	长石	岩屑	泥质含量(%)	成熟度	指数	成熟度	排替压力(MPa)	中值压力(MPa)	平均孔喉半径(μm)	岩石类型
浅海砂坝	C-12	Ⅱ	10	8.2	62	8.0	52.5	5.2	6.3	17.6	低	7.3	极高	/	/	/	长石石英粉砂岩-石英粉砂岩
浅海砂坝	A-3	Ⅰ	18	2.9	48	4.8	58.0	4.2	3.8	19.6	低	7.3	极高	3.60	22.59	0.07	长石石英粉砂岩
浅海重力流	A-2	Ⅰ	15	16.4	88	10.5	57.7	4.0	7.5	2.9	高	5.1	高	0.42	2.05	0.57	岩屑石英极细砂岩
	A-2	Ⅱ	38	19.3	65	5.4	62.9	4.1	8.5	0.5	高	5.1	高	0.41	1.15	0.73	岩屑石英极细砂岩
	A-4	Ⅰ	23	18.7	165	7.7	58.1	3.9	11.4	0.7	高	4.1	高	0.19	0.74	1.44	岩屑石英细砂岩
	A-5	Ⅰ	28	14.2	231	3.2	58.0	7.5	11.9	0.9	高	3.1	中	0.36	2.25	0.66	岩屑石英细砂岩
	A-6	Ⅱ	44	19.6	71	6.0	61.5	3.0	0.8	1.2	高	5.0	高	0.37	1.33	0.74	岩屑石英极细砂岩
	A-7	Ⅰ	20	20.0	79	3.8	57.3	5.4	3.2	0.5	高	3.1	中	0.17	3.18	1.41	岩屑石英细-极细砂岩
	A-7	Ⅱ	37	19.0	123	4.7	57.2	5.3	13.5	1.1	高	3.1	中	0.17	0.99	1.54	岩屑石英细-极细砂岩
	A-8	Ⅰ	8	15.5	188	5.6	54.3	4.3	14.3	8.0	中	2.6	中	/	/	/	岩屑石英极细-细砂岩
	A-8	Ⅱ	18	17.5	90	4.5	54.3	6.1	15.1	3.1	高	2.6	中	/	/	/	岩屑石英细-极细砂岩
	B-1	Ⅱ	20	12.1	99	2.1	62.9	8.5	13.3	1.2	高	2.9	中	/	/	/	长石岩屑石英极细砂岩
	B-2	Ⅱ	10	10.7	125	3.1	61.1	5.7	8.9	10.5	低	4.4	高	0.17	5.72	1.39	石英细-极细砂岩
	B-4	Ⅰ	20	15.9	135	8.9	45.6	6.6	13.9	3.3	中	2.3	中	0.11	1.64	2.35	长石岩屑石英细砂岩
	B-6	Ⅰ	10	15.8	193	5.2	42.5	5.4	13.8	3.3	高	2.2	中	0.71	0.19	4.48	岩屑石英中-细砂岩
	B-6	Ⅱ	8	15.1	146	5.0	49.9	6.3	12.9	6.4	高	2.6	中	0.29	2.00	1.43	岩屑石英细-极细砂岩
	B-8	Ⅰ	29	18.7	154	4.9	52.9	6.9	12.1	2.1	高	2.8	中	0.10	0.58	3.31	长石岩屑石英细砂岩

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附表 1 黄流组砂岩主量元素含量(%)

附表 1. The concentrations of major element for the sandstones from Huangliu Formation (%)

样号	Na₂O	MgO	Al₂O₃	SiO₂	P₂O₅	K₂O	CaO	TiO₂	MnO	Fe₂O₃	FeO	Fe₂O₃/ Total	LOI	SUM	Al₂O₃/TiO₂	SiO₂/Al₂O₃
1	1.24	2.17	12.20	65.72	0.15	2.69	3.51	0.74	0.06	1.54	3.60	5.54	5.76	99.38	16.49	5.39
2	1.09	1.90	10.57	71.15	0.12	2.25	2.78	0.69	0.05	1.34	3.25	4.96	4.62	99.82	15.38	6.73
3	0.98	1.23	7.93	77.40	0.12	1.78	2.74	0.53	0.04	0.98	2.20	3.43	3.86	99.80	15.00	9.76
4	0.97	1.08	6.69	75.37	0.10	1.72	5.08	0.45	0.08	0.53	2.15	2.92	5.31	99.55	14.73	11.27
5	1.10	1.56	8.81	75.08	0.11	2.11	2.31	0.58	0.04	0.95	3.10	4.39	3.74	99.49	15.25	8.52
6	1.04	1.34	7.74	77.63	0.10	2.01	2.47	0.52	0.04	0.71	2.65	3.65	3.59	99.84	14.88	10.03
7	0.90	1.11	6.84	82.42	0.10	1.77	0.99	0.62	0.02	0.64	2.20	3.08	2.31	99.92	11.03	12.05
8	0.93	1.16	7.32	80.55	0.10	1.90	1.72	0.43	0.04	0.60	2.45	3.32	2.73	99.93	17.02	11.00
9	0.82	1.03	6.70	82.79	0.09	1.77	1.07	0.50	0.03	0.65	2.05	2.93	2.14	99.64	13.40	12.36
10	1.25	1.46	7.76	75.72	0.10	1.72	2.20	0.56	0.05	0.44	2.87	3.63	5.66	99.79	13.86	9.76
11	1.28	1.59	8.08	73.33	0.10	1.78	2.86	0.58	0.07	0.70	2.90	3.92	6.20	99.47	13.93	9.08
12	1.19	1.76	11.65	70.67	0.12	1.80	2.13	0.72	0.07	1.16	2.77	4.23	5.50	99.52	16.07	6.07
13	1.42	1.57	10.43	73.05	0.12	1.80	2.12	0.71	0.03	0.99	2.50	3.77	4.92	99.66	14.69	7.00
14	1.10	1.97	13.05	62.87	0.13	2.65	3.36	1.00	0.04	1.39	4.15	6.00	7.73	99.44	13.05	4.82
15	0.97	1.74	12.35	62.80	0.13	2.18	5.96	0.78	0.05	1.26	3.15	4.76	8.49	99.86	15.83	5.09
16	1.08	1.32	7.57	78.18	0.10	1.87	1.47	0.60	0.04	0.68	2.60	3.57	4.49	100.00	12.62	10.33
17	1.32	1.68	8.86	73.13	0.10	2.10	2.23	0.60	0.04	0.67	3.20	4.23	5.93	99.86	14.77	8.25
18	1.28	1.57	8.40	74.37	0.10	2.01	1.91	0.60	0.04	0.71	2.87	3.90	5.45	99.31	14.00	8.85
19	1.30	1.61	8.51	74.15	0.10	2.02	1.99	0.60	0.03	0.68	2.90	3.90	5.62	99.52	14.17	8.72
20	1.19	1.59	8.39	74.71	0.10	2.05	1.81	0.60	0.04	0.75	3.10	4.19	5.44	99.77	13.98	8.90
21	1.18	1.51	8.19	75.76	0.10	1.98	1.65	0.59	0.04	0.67	2.83	3.81	5.05	99.55	13.88	9.25
22	1.28	1.93	9.71	70.15	0.12	2.26	2.19	0.73	0.05	1.73	3.00	5.06	6.60	99.75	13.30	7.22
23	1.29	1.76	8.73	72.30	0.10	1.99	2.40	0.63	0.05	0.92	3.10	4.36	6.26	99.53	13.86	8.28
24	1.24	1.50	8.24	75.17	0.09	1.91	2.37	0.52	0.04	0.30	2.85	3.46	5.48	99.71	15.84	9.13
25	1.10	1.43	7.86	76.30	0.11	1.87	2.07	0.60	0.04	0.69	2.65	3.63	5.17	99.89	13.10	9.71
26	1.18	1.53	8.53	74.58	0.10	2.04	2.14	0.55	0.04	0.66	2.90	3.88	5.47	99.72	15.51	8.74
27	1.21	1.49	8.45	74.98	0.10	2.04	1.80	0.57	0.04	0.78	2.85	3.95	5.27	99.58	14.82	8.87
28	1.03	1.54	8.24	74.58	0.10	2.00	2.39	0.55	0.04	0.58	2.97	3.88	5.71	99.73	14.98	9.05

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附表 2 黄流组砂岩主量、微量元素相关系数矩阵

附表 2. Correlation coefflcient matrix of chemical elements in the samples

	Na₂O	MgO	Al₂O₃	SiO₂	P₂O₅	K₂O	CaO	TiO₂	MnO	Fe₂O₃	FeO	CO₂	Lost	Sc	Cu	Rb	Zr	Hf	Th	U	Ba	Cr	Ni	Sr	V	B
Na₂O	1.00
MgO	0.59	1.00
Al₂O₃	0.29	0.84	1.00
SiO₂	-0.37	-0.86	-0.91	1.00
P₂O₅	0.10	0.69	0.84	-0.76	1.00
K₂O	0.18	0.79	0.73	-0.73	0.69	1.00
CaO	-0.11	0.29	0.47	-0.67	0.53	0.30	1.00
TiO₂	0.26	0.75	0.88	-0.81	0.72	0.68	0.30	1.00
MnO	0.11	0.26	0.22	-0.40	0.26	0.03	0.61	0.03	1.00
Fe₂O₃	0.13	0.73	0.79	-0.71	0.86	0.70	0.33	0.76	0.21	1.00
FeO	0.43	0.88	0.75	-0.81	0.53	0.86	0.29	0.72	0.14	0.52	1.00
CO₂	0.53	0.56	0.46	-0.69	0.16	0.31	0.40	0.51	0.27	0.20	0.58	1.00
Lost	0.49	0.71	0.64	-0.87	0.41	0.47	0.61	0.62	0.40	0.39	0.69	0.93	1.00
Sc	0.29	0.81	0.71	-0.75	0.73	0.84	0.30	0.75	0.12	0.75	0.76	0.44	0.58	1.00
Cu	0.32	0.88	0.84	-0.87	0.74	0.88	0.44	0.75	0.17	0.67	0.88	0.49	0.67	0.81	1.00
Rb	0.02	0.60	0.68	-0.64	0.50	0.76	0.23	0.65	-0.24	0.52	0.74	0.40	0.49	0.60	0.75	1.00
Zr	-0.07	0.34	0.58	-0.51	0.45	0.48	0.19	0.83	-0.15	0.44	0.52	0.34	0.37	0.50	0.48	0.56	1.00
Hf	-0.08	0.33	0.57	-0.49	0.44	0.46	0.18	0.83	-0.15	0.43	0.50	0.32	0.36	0.48	0.47	0.55	1.00	1.00
Th	-0.13	0.44	0.67	-0.61	0.58	0.63	0.33	0.82	-0.08	0.51	0.62	0.30	0.40	0.58	0.64	0.68	0.95	0.94	1.00
U	-0.06	0.55	0.77	-0.72	0.69	0.71	0.41	0.87	0.02	0.63	0.68	0.35	0.48	0.66	0.74	0.72	0.90	0.90	0.98	1.00
Ba	0.42	0.18	0.03	-0.15	-0.13	-0.15	0.01	0.09	0.30	-0.14	0.20	0.42	0.33	0.01	0.09	-0.10	0.06	0.07	-0.00	0.02	1.00
Cr	-0.03	0.64	0.74	-0.66	0.73	0.77	0.28	0.85	-0.01	0.74	0.70	0.20	0.36	0.74	0.77	0.66	0.80	0.80	0.89	0.91	-0.02	1.00
Ni	0.34	0.87	0.71	-0.74	0.65	0.86	0.25	0.66	0.10	0.75	0.83	0.41	0.57	0.85	0.86	0.70	0.35	0.33	0.48	0.59	-0.02	0.72	1.00
Sr	-0.06	0.31	0.50	-0.68	0.52	0.31	0.93	0.38	0.56	0.39	0.30	0.46	0.63	0.29	0.42	0.25	0.26	0.25	0.35	0.44	0.09	0.32	0.30	1.00
V	0.21	0.85	0.86	-0.86	0.80	0.90	0.42	0.85	0.14	0.79	0.87	0.42	0.61	0.88	0.93	0.76	0.64	0.63	0.77	0.85	0.05	0.91	0.89	0.45	1.00
B	0.57	0.73	0.54	-0.63	0.38	0.63	0.09	0.62	-0.08	0.48	0.70	0.66	0.67	0.63	0.69	0.60	0.35	0.34	0.37	0.43	0.07	0.44	0.69	0.16	0.64	1.00

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附表 3 黄流组砂岩稀土元素含量(10^-6)

附表 3. The concentrations of rare earth element for the sandstones from Huangliu Formation (10^-6)

样号	La	Ce	Pr	Nd	Sm	Eu	Gd	Tb	Dy	Ho	Er	Tm	Yb	Lu	Y	SUM	LREE	HREE	LREE/HREE	Eu/Eu^*	(La/Yb)_N	(Gd/Yb)_N
1	41.35	77.82	9.11	33.99	6.26	1.20	5.25	0.89	4.76	0.94	2.69	0.41	2.50	0.36	25.19	212.71	169.72	17.80	9.53	0.64	11.15	1.69
2	36.98	71.17	8.37	31.33	5.74	1.10	4.96	0.81	4.43	0.89	2.46	0.37	2.21	0.32	22.66	193.78	154.69	16.43	9.42	0.63	11.29	1.81
3	29.84	58.47	6.78	25.69	4.76	0.98	4.18	0.69	3.71	0.72	2.02	0.30	1.78	0.26	18.74	158.91	126.52	13.65	9.27	0.67	11.29	1.89
4	28.31	56.14	6.60	25.88	4.87	1.02	4.36	0.74	3.93	0.77	2.13	0.31	1.89	0.27	20.04	157.26	122.82	14.40	8.53	0.68	10.08	1.86
5	28.90	56.11	6.62	25.21	4.45	0.92	4.00	0.66	3.52	0.69	1.92	0.29	1.73	0.26	17.91	153.18	122.21	13.06	9.36	0.67	11.24	1.86
6	27.30	53.90	6.37	24.15	4.48	0.90	3.98	0.66	3.54	0.69	1.93	0.30	1.69	0.27	17.62	147.76	117.09	13.05	8.97	0.65	10.89	1.90
7	38.18	74.92	8.66	32.32	5.90	1.02	4.97	0.78	4.12	0.80	2.29	0.36	2.11	0.30	20.96	197.69	161.00	15.73	10.23	0.57	12.19	1.90
8	27.17	54.06	6.23	23.90	4.51	0.95	3.99	0.65	3.35	0.64	1.85	0.26	1.56	0.24	16.53	145.89	116.82	12.54	9.32	0.68	11.76	2.07
9	27.59	58.86	6.27	23.93	4.61	0.79	4.32	0.72	4.04	0.83	2.45	0.41	2.60	0.41	25.17	163.00	122.05	15.78	7.73	0.54	7.15	1.34
10	28.70	56.96	6.91	26.25	4.78	0.91	4.26	0.68	3.67	0.76	2.03	0.30	1.83	0.27	18.62	156.93	124.51	13.80	9.02	0.62	10.58	1.88
11	29.53	58.02	6.96	26.54	4.92	0.95	4.13	0.67	3.65	0.72	2.00	0.30	1.69	0.26	18.16	158.50	126.92	13.42	9.46	0.65	11.79	1.97
12	31.51	59.88	7.19	26.96	4.94	0.98	4.30	0.70	3.64	0.75	2.04	0.32	1.87	0.29	18.68	164.04	131.46	13.89	9.46	0.65	11.38	1.86
13	36.58	69.38	8.25	31.09	5.51	1.06	4.67	0.74	4.05	0.80	2.26	0.34	2.00	0.29	20.44	187.44	151.87	15.13	10.03	0.64	12.36	1.89
14	77.28	146.47	16.81	61.99	10.99	1.56	9.05	1.40	7.31	1.52	4.02	0.62	3.85	0.57	37.73	381.16	315.09	28.34	11.12	0.48	13.55	1.90
15	40.67	78.87	9.19	34.45	6.29	1.12	5.36	0.87	4.66	0.97	2.69	0.41	2.51	0.38	24.66	213.10	170.59	17.85	9.56	0.59	10.94	1.73
16	32.67	62.62	7.38	27.96	5.07	1.00	4.29	0.69	3.63	0.71	2.03	0.29	1.72	0.25	17.99	168.28	136.69	13.60	10.05	0.66	12.78	2.01
17	31.15	58.76	7.17	27.18	4.84	0.99	4.20	0.69	3.63	0.73	2.04	0.30	1.97	0.27	19.21	163.14	130.10	13.83	9.41	0.67	10.64	1.72
18	31.12	58.50	7.14	27.00	4.90	0.98	4.28	0.70	3.79	0.75	2.08	0.31	1.81	0.28	19.58	163.22	129.64	14.00	9.26	0.66	11.62	1.91
19	30.81	59.03	7.10	27.15	4.92	0.99	4.17	0.70	3.76	0.74	2.02	0.33	1.96	0.27	19.09	163.05	130.00	13.95	9.32	0.67	10.60	1.72
20	30.99	60.50	7.18	27.32	4.97	0.98	4.25	0.68	3.62	0.71	1.99	0.30	1.73	0.26	17.79	163.24	131.93	13.52	9.75	0.65	12.11	1.99
21	31.40	60.56	7.26	27.22	5.08	1.01	4.24	0.71	3.79	0.72	2.06	0.31	1.86	0.28	19.06	165.55	132.53	13.96	9.50	0.67	11.36	1.83
22	38.51	69.70	8.48	31.83	5.74	1.13	5.14	0.86	4.78	0.96	2.69	0.43	2.67	0.41	26.15	199.49	155.40	17.94	8.66	0.64	9.72	1.55
23	31.41	57.19	7.15	27.25	5.30	1.02	4.81	0.84	4.59	0.91	2.60	0.40	2.53	0.37	23.24	169.62	129.32	17.05	7.58	0.62	8.36	1.53
24	24.15	46.12	5.50	21.04	3.89	0.81	3.45	0.56	2.98	0.58	1.69	0.25	1.46	0.21	15.64	128.35	101.52	11.19	9.08	0.68	11.15	1.91
25	36.05	61.28	7.89	29.54	5.46	1.04	4.68	0.84	4.51	0.87	2.58	0.43	2.47	0.38	23.11	181.12	141.27	16.74	8.44	0.63	9.85	1.53
26	30.22	56.66	6.83	25.82	4.67	1.00	4.10	0.68	3.62	0.71	2.00	0.29	1.76	0.26	18.01	156.63	125.20	13.42	9.33	0.70	11.55	1.88
27	27.38	52.71	6.28	23.84	4.24	0.91	3.89	0.61	3.28	0.64	1.83	0.28	1.75	0.25	16.83	144.72	115.36	12.53	9.21	0.69	10.54	1.79
28	29.46	56.54	6.73	25.44	4.67	0.96	3.97	0.65	3.61	0.70	1.94	0.30	1.79	0.26	18.11	155.13	123.79	13.23	9.36	0.68	11.12	1.79

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附表 4 黄流组砂岩微量元素含量(10^-6)

附表 4. The concentrations of trace element for the sandstones from Huangliu Formation (10^-6)

样号	Sc	Co	Cu	Rb	Zr	Hf	Th	U	Ba	Cr	Ni	Sr	V	B	Cr/Ni	Th/Sc	Cr/Th	La/Sc
1	11.61	11.92	13.04	84.14	266.1	8.60	12.30	2.00	424.1	68.43	28.52	141.3	81.99	64.79	2.40	1.06	5.56	3.56
2	9.45	11.76	10.70	76.26	280.9	9.57	12.14	1.80	454.1	71.72	27.85	129.0	77.44	58.57	2.58	1.28	5.91	3.91
3	7.08	8.56	6.48	73.76	227.8	7.25	9.57	1.47	335.1	55.84	22.11	131.2	57.05	45.82	2.53	1.35	5.84	4.21
4	6.35	5.83	5.14	42.32	187.5	6.23	7.93	1.23	320.7	48.27	15.18	179.9	47.86	35.81	3.18	1.25	6.09	4.46
5	7.25	9.06	7.60	80.17	220.9	7.54	9.71	1.45	360.8	56.82	21.19	111.2	61.81	54.49	2.68	1.34	5.85	3.99
6	6.63	7.27	6.38	74.87	204.9	6.78	8.50	1.33	394.9	51.87	18.70	118.4	54.78	43.24	2.77	1.28	6.10	4.12
7	6.24	6.36	5.82	65.22	447.5	15.27	12.84	1.63	325.8	61.43	15.72	77.21	51.57	42.11	3.91	2.06	4.78	6.12
8	6.16	7.79	6.02	74.74	168.0	5.42	8.11	1.33	365.3	49.76	19.21	94.75	49.88	33.33	2.59	1.32	6.13	4.41
9	6.89	6.01	4.68	66.60	216.6	7.23	7.98	1.16	425.3	52.62	16.86	83.64	48.08	32.00	3.12	1.16	6.60	4.01
10	7.03	8.39	7.51	67.07	240.5	8.27	8.56	1.32	1008	52.73	19.06	122.1	57.76	54.07	2.77	1.22	6.16	4.09
11	7.34	8.53	7.14	65.66	254.1	8.75	9.05	1.41	1033	55.00	19.48	125.9	57.33	44.74	2.82	1.23	6.07	4.02
12	7.03	8.47	7.50	68.19	300.4	10.09	9.50	1.54	513.2	54.28	19.56	114.6	58.02	45.35	2.78	1.35	5.72	4.48
13	7.20	7.78	6.95	66.40	329.8	11.27	10.24	1.53	448.2	55.41	18.24	108.4	56.90	61.20	3.04	1.42	5.41	5.08
14	11.43	13.36	12.84	110.5	887.8	29.35	25.73	3.39	533.4	83.09	28.67	149.2	91.33	75.64	2.90	2.25	3.23	6.76
15	8.75	10.61	10.80	99.77	402.2	13.27	14.07	2.13	484.6	62.76	23.62	223.2	72.89	61.49	2.66	1.61	4.46	4.65
16	6.85	6.66	5.80	63.31	307.7	10.14	8.14	1.26	519.3	53.86	18.71	115.6	54.28	57.70	2.88	1.19	6.62	4.77
17	8.54	9.89	7.99	76.89	237.5	7.50	8.40	1.22	487.3	53.83	23.40	106.8	58.29	59.62	2.30	0.98	6.41	3.65
18	8.05	8.65	7.75	64.55	261.6	8.40	9.61	1.48	704.3	53.98	21.35	118.1	58.24	57.57	2.53	1.19	5.62	3.87
19	8.51	9.06	7.97	75.05	254.3	8.15	8.76	1.41	426.3	55.14	22.62	110.5	60.82	51.10	2.44	1.03	6.30	3.62
20	7.26	8.94	6.98	74.86	272.3	8.87	9.07	1.34	460.6	54.23	22.39	108.2	57.63	61.07	2.42	1.25	5.98	4.27
21	7.29	8.45	7.31	77.93	273.1	9.23	10.02	1.45	469.6	54.75	21.30	117.4	58.64	65.27	2.57	1.37	5.46	4.31
22	10.28	11.80	9.72	83.33	290.9	9.36	9.26	1.65	463.9	60.45	27.56	113.6	69.70	81.79	2.19	0.90	6.53	3.75
23	8.42	9.84	8.23	72.10	216.0	6.72	7.85	1.30	450.6	55.20	25.66	127.7	62.79	63.72	2.15	0.93	7.03	3.73
24	6.50	7.85	9.42	74.86	176.0	5.84	8.20	1.26	569.8	48.54	19.55	101.5	54.14	66.47	2.48	1.26	5.92	3.71
25	9.63	7.52	6.45	70.72	287.3	9.39	9.20	1.32	418.5	51.93	19.31	96.45	56.41	57.88	2.69	0.96	5.65	3.74
26	7.93	8.37	8.16	76.57	198.7	6.84	8.29	1.19	373.8	52.93	21.54	98.16	59.05	54.68	2.46	1.05	6.38	3.81
27	7.28	8.82	7.76	80.59	201.3	6.59	8.33	1.31	384.0	53.08	21.28	121.5	57.37	69.53	2.49	1.14	6.38	3.76
28	7.34	9.47	8.01	86.61	217.4	7.25	10.28	1.51	343.8	54.53	21.02	98.16	59.63	60.61	2.59	1.40	5.30	4.01

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表 2 黄流组浅海重力流砂岩微量元素与长英质源岩、铁镁质源岩以及上地壳对比

Table 2. Comparison of elemental ratio of sediments from Huangliu Formation, felsic sources, mafic sources and upper continental crust

元素比值	黄流组	长英质源岩(据Amstrong-Altrin，2004)	铁镁质源岩(据Amstrong-Altrin，2004)	上地壳(据Rudnick and Gao, 2003)
La/Sc	3.56~6.76(4.25*)	2.50~16.30	0.43~0.86	2.21
Th/Sc	0.90~2.25(1.28*)	0.84~20.50	0.05~0.22	0.75
Cr/Th	3.23~7.03(5.84*)	4.00~15.00	25.00~500.00	8.76
δEu	0.48~0.70(0.64*)	0.40~0.94	0.71~0.95	0.72
注：上标注*的为平均值.

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表 3 黄流组浅海重力流砂岩微量元素与不同构造环境对比

Table 3. Comparison of trace and rare earth elements of sediments from different tectonic settings

	大洋岛弧	大陆岛弧	主动大陆边缘	被动大陆边缘	黄流组(平均值)
微量元素(Bhatia, 1985)
Th(10^-6)	5.5	16.2	28.0	22.0	10.1
U(10^-6)	2.4	3.2	6.0	3.6	1.5
La/Sc	1.0	1.8	2.5	1.9	4.3
Ni(10^-6)	15.0	18.0	26.0	36.0	21.4
Sc/Ni	1.70	0.96	0.75	0.45	0.37
稀土元素(Bhatia, 1985)
La(10^-6)	8.0	27.0	37.0	39.0	33.4
Ce(10^-6)	19.0	59.0	78.0	85.0	63.9
ΣREE	58.0	146.0	186.0	210.0	175.5
(La/Yb)_N	2.8	7.5	8.5	10.8	11.0
Eu/Eu^*	1.04	0.78	0.60	0.56	0.64

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