海南岛晨星早石炭世高度亏损N-MORB型玄武岩及其地质意义

何慧莹; 王岳军; 张玉芝; 陈新跃; 周永智

doi:10.3799/dqkx.2016.108

海南岛晨星早石炭世高度亏损N-MORB型玄武岩及其地质意义

doi: 10.3799/dqkx.2016.108

何慧莹^1,2,,
王岳军^1,2, ,,
张玉芝^1,2,
陈新跃³,
周永智^1,2

1.
中山大学地球科学与地质工程学院，广东广州 510275
2.
广东省地质过程与矿产资源探查重点实验室，广东广州 510275
3.
湖南科技大学地质系，湖南湘潭 411201

基金项目:

国家重点基础研究发展计划(973计划) 2014CB440901

国家自然科学基金项目 41190073

详细信息

作者简介:
何慧莹(1993-)，女，硕士研究生，主要从事岩石大地构造研究.E-mail: hehuiy2@mail2.sysu.edu.cn

通讯作者:
王岳军, E-mail: wangyuejun@mail.sysu.edu.cn

中图分类号: P581
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出版历程
- 收稿日期: 2016-02-06
- 刊出日期: 2016-08-15

Extremely Depleted Carbonferous N-MORB Metabasite at the Chenxing Area (Hainan) and Its Geological Significance

He Huiying^{1,2
,},
Wang Yuejun^{1,2
, ,},
Zhang Yuzhi^1,2,
Chen Xinyue³,
Zhou Yongzhi^1,2

1.
School of Earth Sciences and Geological Engineering, Sun Yat-Sen University, Guangzhou 510275, China
2.
Guangdong Provincial Key Laboratoroy of Mineral Resources & Geological Processes, Guangzhou 510275, China
3.
Department of Geology, Hunan University of Science and Technology, Xiangtan 411201, China

摘要

摘要: 海南岛地处印支陆块和华南陆块的交界地带，具有复杂的构造演化史，其拼合机制及精细时代一直备受争议.在海南岛昌江-琼海断裂以北的晨星地区识别出一套具高ε_Nd(t)值的火山岩，对其进行了全岩⁴⁰Ar-³⁹Ar年代学及主、微量元素和同位素地球化学研究.结果表明，该火山岩的全岩⁴⁰Ar-³⁹Ar坪年龄为328.1±2.6 Ma，代表了其喷发年龄；该变基性岩SiO₂含量为46.92%~52.58%，具有低TiO₂、低K₂O、高Al₂O₃的特征；稀土元素丰度为15.1×10^-6~28.7×10^-6, 呈现N-MORB型微量元素配分曲线, ε_Nd(t)高至9.02~9.85，显示出高度亏损的地球化学特征；其成因被解释为源于受流体交代作用改造的MORB型地幔源区.综合分析表明晨星地区变基性岩的形成可能与古特提斯洋陆俯冲格局下华南与印支陆块间的弧后盆地或有限洋演变有关.
- 变基性岩 /
- Nd同位素 /
- N-MORB /
- 石炭纪 /
- 东古特提斯演化 /
- 地球化学 /
- 岩石学
Abstract: Hainan Island, located between the Indochina and South China Blocks, has undergone compound structural overprinting and complex tectonic evolution. However, the Late Paleozoic tectonic regime and amalgamation history of the South China with Indochina Blocks are still on debate. Our investigation identified the highly-depleted greenschist-facies basalt at the Chenxing area in the north of the Changjiang-Qionghai fault, Central Hainan Island. This paper presents a set of new geochronological and geochemical data for these metabasites. The representative sample for Chenxing metabasites gave the plateau age of 328.1±2.6 Ma, representing the eruption age. They have SiO₂ ranging from 46.92 % to 52.58 %, TiO₂ from 0.48 % to 1.12% and Al₂O₃ from 12.34 % to 17.45 %, and could be classified as basalt. These samples show lower K₂O contents, and HFSEs and REEs contents relative to N-MORB. They are characterized by the left-sloping REE pattern and multi-elemental pattern with a geochemical affinity to N-MORB. These samples show extremely high ε_Nd(t) values ranging from 9.02 to 9.85. Such geochemical characteristics for the Chenxing metabasites show the derivation of the MORB source modified by slab-related fluid. In combination with other available data, the Chenxing metabasites in Central Hainan are formed in the back-arc basin or a restricted ocean basin between the South China and Indochina blocks during the Carboniferous in response to the subduction of the Paleotethyan main ocean.
- metabasites /
- Nd isotopic composition /
- N-MORB /
- Carbonferous /
- eastern paleotethyan evolution /
- geochemistry /
- petrology

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图 1 华南南缘大地构造略图(a)和海南晨星地区地质概况及采样点位置(b)

Fig. 1. Geological sketch in South China (a) and geological sketch of the Chenxing area showing the sampling locations (b)

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图 2 晨星地区变基性岩野外照片(a)，变基性岩手标本(b)和岩石显微相片(c)

Amp.角闪石；Pl.斜长石；Aug.辉石

Fig. 2. Field photograph (a), metabasite hand specimens (b) and photomicrograph (c) of the Chenxing metabasite, Central Hainan

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图 3 晨星变基性岩样品11HN-48B的⁴⁰Ar-³⁹Ar坪年龄

Fig. 3. ⁴⁰Ar-³⁹Ar age spectra of the Chenxing metabasite sample (11HN-48B), Central Hainan

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图 4 晨星变基性岩SiO₂-K₂O+Na₂O(a)和SiO₂-(Zr/TiO₂)(b)关系

图a据Maitre et al.(1989)；图b据Winchester and Floyd(1977)

Fig. 4. Relations of SiO₂-K₂O+Na₂O (a) and SiO₂-Zr/TiO₂ (b) from the Chenxing metabasites

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图 5 晨星变基性岩MgO与SiO₂(a), CaO/Al₂O₃(b), Al₂O₃(c), TFe₂O₃(d), TiO₂(e), P₂O₅(f), Cr(g)和Ni(h)相关图解

所有氧化物值均已100%无水化

Fig. 5. MgO versus SiO₂ (a), CaO/ Al₂O₃ (b), Al₂O₃ (c), TFe₂O₃ (d), TiO₂ (e), P₂O₅ (f), Cr (g) and Ni (h) for the Chenxing metabasite

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图 6 晨星变基性岩的球粒陨石标准化稀土元素配分模式(a)和标准化微量元素蛛网图(b)

勉略鞍子山斜长角闪岩数据来自许继峰等(1997, 2000)；新元古代南桥玄武岩来自Zhang et al.(2013), 其中球粒陨石和N-MORB数据分别引自Taylor and McLennan(1995)和Sun and McDonough(1989)

Fig. 6. Chondrite-normalized REE pattern (a) and N-MORB-normalized trace element spider diagram (b) of the Chenxing metabasite

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图 7 晨星地区变基性岩⁸⁷Sr/⁸⁶Sr(t)-ε_Nd(t)关系

双沟和金沙江蛇绿岩数据来自Jian et al.(2009a, 2009b)

Fig. 7. Relation of ⁸⁷Sr/⁸⁶Sr(t)-ε_Nd(t) from the Chenxing metabasites, Central Hainan

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图 8 晨星变基性岩的Nb/La-MgO和ε_Nd(t)-MgO关系

据Zhang et al.(2013)修改

Fig. 8. Relations of Nb/La-MgO (a) and ε_Nd(t)-MgO (b) from the Chenxing metabasites

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图 9 晨星变基性岩的U/Th-Th(a)和Th/Yb-Ba/La(b)关系

勉略鞍子山变基性岩数据来自许继峰等(1997, 2000)；新元古代南桥玄武岩来自Zhang et al.(2013)

Fig. 9. Relations of U/Th-Th (a) and Th/Yb-Ba/La (b) from the Chenxing metabasites

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图 10 晨星地区变基性岩的地球化学判别关系

a.图版据Pearce and Cann(1973)；b.图版据Meschede(1986)；c.图版据Cabanis and Lecolle(1989)；d.图版据Wood(1980).勉略鞍子山变基性岩数据来自许继峰等(1997, 2000)；新元古代南桥玄武岩来自Zhang et al.(2013)

Fig. 10. Geochemical discrimination relations for the Chenxing metabasite

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图 11 晨星变基性岩Ti-Zr/1 000(a), Ti/Zr-Zr(b), V-Ti/1 000(c)和(Tb/Ta)_N-(Th/Ta)_N(d)关系

a.图版据Pearce(1982)；b.图版据Wang et al.(2013)；c.图版据Shervais(1982).勉略鞍子山变基性岩数据来自许继峰等(1997, 2000)；新元古代南桥玄武岩来自Zhang et al.(2013)

Fig. 11. Relations of Zr-Ti/1 000 (a), Ti/Zr-Zr (b), V-Ti/1 000 (c) and (Tb/Ta)_N-(Th/Ta)_N (d) from the Chenxing metabasites

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表 1 晨星地区代表性变基性岩样品(11HN-48B)的全岩⁴⁰Ar-³⁹Ar同位素逐步加热结果

Table 1. Whole-rock ⁴⁰Ar-³⁹Ar isotopic analyses for incremental heating experiments for the Chenxing metabasite (11HN-48B) in Central Hainan

温度	(⁴⁰Ar/³⁶Ar)_m	(³⁹Ar/³⁶Ar)_m	(³⁷Ar/³⁹Ar)_m	(^40*Ar/³⁹Ar)_k	^40*Ar(%)	³⁹Ar_k(%)	表观年龄(t±2σ)Ma
700 ℃	415.923 85	1.129 45	0.007 08	82.172 836	19.76	0.85	390.6±34.2
750 ℃	126.050 85	0.196 47	0.013 24	67.996 157	53.94	2.49	328.9±6.5
800 ℃	73.232 48	0.021 10	0.001 56	66.996 182	91.48	3.69	324.5±2.0
840 ℃	73.851 99	0.018 87	0.000 67	68.276 230	92.45	7.64	330.2±2.0
880 ℃	70.559 04	0.008 08	0.000 35	68.171 792	96.62	23.17	329.7±2.1
910 ℃	66.323 84	0.003 21	0.001 64	65.375 672	98.57	11.09	317.3±1.9
940 ℃	67.343 12	0.004 38	0.000 68	66.048 891	98.08	6.78	320.3±1.9
980 ℃	68.582 39	0.006 12	0.003 67	66.773 588	97.36	5.22	323.5±2.0
1 020 ℃	69.910 83	0.005 65	0.002 97	68.241 524	97.61	4.62	330.0±2.0
1 060 ℃	70.430 95	0.005 71	0.000 51	68.743 569	97.60	5.23	332.3±2.0
1 100 ℃	69.406 28	0.004 33	0.001 10	68.127 615	98.16	8.80	329.5±2.1
1 140 ℃	67.976 53	0.002 24	0.001 02	67.315 073	99.03	16.64	325.9±2.0
1 170 ℃	70.676 69	0.001 93	0.004 71	70.105 585	99.19	3.09	338.3±2.0
1 220 ℃	77.837 60	0.006 63	0.036 45	75.882 506	97.49	0.46	363.5±2.3
1 400 ℃	92.278 05	0.025 63	0.065 83	84.715 839	91.80	0.24	401.4±32.3
注：m.样品中测定的同位素比值；*.表示放射成因；k.中子活化过程中由³⁹K产生的³⁹Ar.

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表 2 晨星地区变基性岩主量(%)和微量元素(10^-6)分析结果

Table 2. Major elements (%) and trace elements (10^-6) analytical results for the Chenxing metabasite

样品	11HN-48A	11HN-48B	11HN-48C	11HN-48D	11HN-48E	11HN-48F	11HN-48G	11HN-48H
SiO₂	46.03	51.84	51.82	47.11	49.14	46.78	48.93	49.40
TiO₂	1.12	0.48	0.55	0.56	0.52	0.63	1.09	0.61
Al₂O₃	17.12	12.43	12.59	14.17	13.89	16.02	14.52	12.08
TFeO	10.59	8.68	9.33	9.62	9.32	10.41	10.72	9.72
MgO	9.08	11.34	10.32	11.01	12.03	10.37	9.50	12.24
CaO	11.69	10.83	11.33	12.07	10.37	11.67	11.54	11.86
K₂O	0.57	0.09	0.07	0.13	0.07	0.10	0.15	0.47
Na₂O	1.64	2.78	2.72	2.34	2.44	2.44	2.08	1.28
MnO	0.19	0.12	0.13	0.15	0.14	0.16	0.17	0.18
P₂O₅	0.07	0.02	0.03	0.03	0.03	0.04	0.07	0.03
LOI	1.40	1.09	0.78	2.45	1.68	0.97	0.78	1.68
Total	99.51	99.70	99.67	99.63	99.63	99.58	99.54	99.54
Sc	40.60	36.50	40.60	41.00	38.50	41.00	42.60	48.00
V	293	212	239	224	225	267	298	274
Cr	476	990	1 010	974	1 140	1 170	404	743
Co	56.7	50.8	57.8	50.4	54.6	64.1	47.1	40.6
Ni	255	270	336	307	360	419	138	191
Ga	16.20	8.81	11.80	12.60	11.40	14.90	14.80	11.10
Rb	24.40	1.94	1.22	3.98	1.54	1.13	3.94	22.40
Sr	249	149	186	206	154	163	188	160
Y	18.80	13.80	16.00	14.70	15.40	19.20	20.90	20.10
Zr	49.50	23.50	27.40	25.40	25.40	28.40	50.70	31.80
Nb	1.49	0.76	0.93	0.80	0.84	1.08	1.36	0.60
Cs	1.49	0.14	0.16	5.20	0.18	0.11	0.34	1.35
Ba	78.00	44.40	49.50	51.20	57.30	53.90	39.50	70.00
La	1.64	0.85	1.14	1.08	0.95	0.98	1.93	0.75
Ce	4.35	2.43	2.97	3.10	2.61	2.98	5.04	2.60
Pr	0.82	0.44	0.50	0.50	0.52	0.53	0.91	0.54
Nd	4.91	2.24	2.81	2.89	2.56	3.11	5.45	3.44
Sm	2.07	1.00	1.15	1.18	1.12	1.24	2.14	1.35
Eu	0.77	0.45	0.60	0.47	0.47	0.56	0.89	0.60
Gd	2.84	1.51	1.83	1.77	1.69	2.02	2.96	2.16
Tb	0.49	0.30	0.37	0.35	0.33	0.40	0.53	0.43
Dy	3.21	2.10	2.58	2.40	2.37	2.90	3.43	3.04
Ho	0.68	0.48	0.59	0.54	0.53	0.66	0.74	0.69
Er	1.97	1.46	1.76	1.61	1.59	1.96	2.11	2.07
Tm	0.29	0.21	0.27	0.24	0.24	0.30	0.31	0.32
Yb	1.82	1.44	1.75	1.56	1.56	1.93	1.95	2.07
Lu	0.27	0.21	0.26	0.23	0.23	0.29	0.29	0.31
Hf	1.38	0.65	0.77	0.75	0.68	0.81	1.36	0.84
Ta	0.10	0.05	0.07	0.06	0.06	0.06	0.09	0.04
Th	0.14	0.09	0.10	0.04	0.03	0.10	0.10	0.08
U	0.16	0.07	0.20	0.11	0.16	0.12	0.18	0.21

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表 3 海南岛晨星地区变基性岩的同位素分析结果

Table 3. The isotopic analytical results for the representative samples from the Chenxing metabasite

样品编号	⁸⁷Rb/⁸⁶Sr	¹⁴⁷Sm/¹⁴⁴Nd	⁸⁷Sr/⁸⁶Sr	2σ	¹⁴³Nd/¹⁴⁴Nd	2σ	(⁸⁷Sr/⁸⁶Sr)_i	(¹⁴³Nd/¹⁴⁴Nd)_i	ε_Nd(t)
11HN-48B	0.038	0.270	0.709 714 42	0.000 000 07	0.513 299	0.000 011	0.709 539	0.512 710	9.85
11HN-48D	0.029	0.265	0.709 639 92	0.000 000 11	0.513 250	0.000 008	0.709 505	0.512 669	9.02
11HN-48F	0.020	0.237	0.708 506 31	0.000 000 15	0.513 202	0.000 011	0.708 413	0.512 685	9.31
11HN-48H	0.405	0.237	0.709 639 92	0.000 000 11	0.513 211	0.000 006	0.707 749	0.512 693	9.48

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