华北克拉通南缘约2.5 Ga构造变质事件及意义

曹正琦; 翟文建; 蒋幸福; 胡正祥; 曾佐勋; 蔡逸涛; 张雄; 徐少朋; 郭君功

doi:10.3799/dqkx.2016.047

华北克拉通南缘约2.5 Ga构造变质事件及意义

doi: 10.3799/dqkx.2016.047

1.
中国地质大学地球科学学院，湖北武汉 430074
2.
湖北省地质调查院，湖北武汉 430034
3.
河南省地质调查院，河南郑州450001
4.
东华理工大学地球科学学院，江西南昌 330013
5.
中国地质调查局南京地质调查中心，江苏南京 210026

基金项目:

中国地质调查局项目 1212011220497

详细信息

作者简介:
曹正琦(1980-)，男，工程师，博士在读，主要从事区域构造方向研究工作. E-mail: czq7651368@163.com

中图分类号: P548
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出版历程
- 收稿日期: 2015-07-12
- 刊出日期: 2016-04-15

About 2.5 Ga Tectono-Metamorphic Event in Southern Margin of North China Craton and Its Significance

1.
School of Earth Sciences, China University of Geosciences, Wuhan 430074, China
2.
Hubei Geological Survey, Wuhan 430034, China
3.
Henan Institute of Geological Survey, Zhengzhou 450001, China
4.
Faculty of Earth Sciences, East China University of Technology, Nanchang 330013, China
5.
Nanjing Center, China Geological Survey, Nanjing 210016, China

摘要

摘要: 林山岩群是华北克拉通中部造山带南缘前寒武纪结晶基底的一部分，它对于探讨中部造山带碰撞时代及其在克拉通南缘的分布具有重要意义.选择林山岩群主体的变基性岩(斜长角闪片岩)为主要研究对象，利用锆石U-Pb定年和岩石地球化学方法，获得的结果表明斜长角闪片岩样品锆石多呈长柱状，且外形不规则，具弱分带、斑杂状分带和扇形分带结构，其中少量锆石保留有早期原岩残留的岩浆核.锆石核部具岩浆振荡环带特征，大部分Th/U比值范围为0.10~9.24，且外形不规则，边部具溶蚀结构；绝大部分锆石具弱分带、斑杂状分带和扇形分带结构，以及低Th/U比值范围为0~0.09，个别比值为0.12，显示为典型的变质锆石特征.LA-ICP-MS锆石U-Pb定年结果表明该斜长角闪片岩的核部残留加权平均年龄为2 528±43 Ma(MSWD=1.5，n=10)，经历变质作用的加权平均时限为2 474±22 Ma(MSWD=1.3，n=21).全岩地球化学结果显示林山岩群变基性岩贫硅(47.70%~50.77%，平均值为48.90%)和低钾(0.56%~1.78%，平均值为1.13%)，轻、重稀土分异较弱，亏损微量元素Nb、Th、Ti、Zr等高场强元素，且具有低的微量元素Zr含量(＜130×10^-6)和Zr/Y比值(＜4).这些特征表明林山岩群形成于俯冲作用背景下的岛弧环境.因此，上述证据共同反映了华北克拉通东、西陆块碰撞产物的中部造山带经历了新太古代晚期-古元古代早期的俯冲碰撞造山作用.
- 古元古代早期 /
- 变质事件 /
- 林山岩群 /
- 华北克拉通 /
- 中部造山带 /
- 同位素 /
- 构造地质学
Abstract: Linshan Group, located in the southern margin of the central orogenic belt of the North China Craton, is a Precambrian basement. It is important to study the collision era of the central orogenic belt and the distribution of the southern margin of the North China Craton. A study was carried out on the metabasite (plagioclase-amphibole schist) of the Linshan Group for the purpose of constraining the collisional time of the central orogenic belt and its distribution through the zircon U-Pb dating and rock geochemical methods. The results obtained show that most of zircon grains from plagioclase-amphibole schist are long columnar, euhedral to subhedral, and show typical core-rim structure with irregular shape, weak zoning, taxitic zoning and sector zoning structure. Some zircons preserve the inherited cores of the early magma. Zircon rims display characteristics of dissolution texture with low Th/U ratios (most of them less than 0.09), however, zircons' cores show typical oscillatory zoning structure and relatively high Th/U ratios ranging from 0.10 to 9.24. The evidence suggests that the zircons of plagioclase-amphibole schist could be metamorphic origin. Relict cores and rims of the zircons from the plagioclase-amphibole schist yield ages of 2 528±43 Ma (MSWD=1.5, n=10) and 2 474±22 Ma (MSWD=1.3, n=21), respectively. The former data represent residual age of protolith, and the latter indicate a circa 2.5 Ga metamorphic event in the central orogenic belt of the North China Craton. Whole-rock geochemical results show that metabasite samples from the Linshan Group have relatively low contents of SiO₂ (47.70%-50.77%, average=48.90%) and K₂O (0.56%-1.78%, average=1.13%), and are depleted in high field strength elements (eg., Nb, Th, Ti and Zr) with flat REE patterns. Moreover, the geochemical samples have low content of Zr (less than 130×10^-6) and ratios of Zr/Y (less than 4), indicating that the Linshan Group could have been formed in the subducted-related island arc environment. Therefore, the above evidence show that the central orogenic belt that formed by the collision orogenesis between eastern block and western block of the North China Craton experienced late Neoarchean to early Paleoproterozoic subduction-collisional event.
- early Paleoproterozoic /
- metamorphic event /
- Linshan Group /
- North China Craton /
- central orogenic belt /
- isotope /
- tectonics

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图 1 华北克拉通构造分区(a)和变质基底分布(b)

据Zhao et al.(1998)

Fig. 1. Tectonic subdivision (a) and distribution of the exposed basement (b) of the North China Craton

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图 2 中部造山带林山岩群地质简图及研究年代样品的位置(实测)

Fig. 2. Geological sketch of Linshan Group located in the southern Central Orogenic Belt of the North China Craton

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图 3 林山岩群斜长角闪片岩野外和显微照片

a.强烈褶皱变形的斜长角闪片岩；b.斜长角闪片岩的线理构造；c, d.斜长角闪片岩的矿物组合(单偏光镜)；e, f.斜长角闪片岩薄片中保留的“S-C”结构(正交镜)，红色箭头指示的是剪切方向

Fig. 3. Field and microstructure photos of plagioclase-amphibole schist of the Linshan Group

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图 4 斜长角闪片岩Zr/TiO₂-Nb/Y判别图解

据Winchester and Floyd(1977)；其中2个样品(灰色三角形，下同)可能遭受了部分熔融作用影响

Fig. 4. Zr/TiO₂ vs.Nb/Y discriminant diagram for the plagioclase-amphibole schist of the Linshan Group

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图 5 斜长角闪片岩稀土元素配分图(a)和微量元素蛛网图(b)

球粒陨石和原始地幔标准化数据来自Sun and McDonough(1989)；灰色线可能遭受了部分熔融作用

Fig. 5. Chondrite-(a) and primitive mantle-(b) normalized diagrams for plagioclase-amphibole schist of Linshan Group

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图 6 界板沟斜长角闪片岩残留核部锆石(a)和变质锆石CL照片及分析位置(b)

红色的圆圈为激光剥蚀的位置，圆圈直径为30 μm

Fig. 6. Cathodoluminescence (CL) images ²⁰⁷Pb/²⁰⁶Pb ages (Ma) for zircon cores (a) and rims (b) from plagioclase-amphibole schist

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图 8 林山岩群斜长角闪片岩中锆石边部(a)和核部U-Pb谐和图(b)

Fig. 8. Concordia plots showing the results of zircon rims (a) and cores (b) from plagioclase-amphibole schist of Linshan Group

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图 7 界板沟斜长角闪片岩残留核部锆石、变质锆石中Th/U和²⁰⁷Pb/²⁰⁶Pb关系

Fig. 7. Th/U ratios vs.²⁰⁷Pb/²⁰⁶Pb ages diagram for zircon grains of plagioclase-amphibole schist

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图 9 斜长角闪片岩微量元素哈克图解

灰色三角可能遭受了部分熔融作用

Fig. 9. Hark diagrams of Zr versus selected trace elements for the plagioclase-amphibole schist of Linshan Group

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图 10 林山岩群斜长角闪片岩构造环境判别

a.Nb-Zr判别图解，修编自Le et al.(1983)；b.Hf/3-Th-Nb判别图解，修编自Wood(1980)；c.不活动元素构造环境判别图解，修编自Agrawal et al.(2008)；d.Th/Yb-La/Yb判别图解，修编自Condie(1989).N-MORB.N型洋中脊玄武岩；IAT.岛弧拉斑玄武岩；CAB.钙碱性玄武岩；E-MORB+WPT.E型洋中脊玄武岩和板内拉斑玄武岩；WAPB.碱性板内玄武岩；IAB.岛弧玄武岩；OIB.洋岛玄武岩；CRB.大陆裂谷玄武岩；PA.初始岛弧；IA.岛弧；CMA.大陆边缘弧；AA.安第斯岛弧

Fig. 10. Tectonic discriminant diagrams for plagioclase-amphibole schist of Linshan Group

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表 1 林山岩群斜长角闪片岩主量(%)及微量元素(10^-6)分析结果

Table 1. Major element (%) and trace element (10^-6) compositions of plagioclase-amphibole schist of Linshan Group

样品	斜长角闪片岩			斜长角闪片岩			斜长角闪片岩
样品	D025/74-1	D026/112-1	D029/84-1	D030/131-1	D135/13-1	D135/20-1	D136/72-1	D703/57-1	D745/6-1
SiO₂	50.77	47.73	48.94	48.15	49.65	48.60	48.05	48.98	49.23
Al₂O₃	13.73	13.83	14.08	13.89	12.34	13.67	15.21	13.41	13.09
TiO₂	0.99	1.55	1.55	1.23	1.70	0.78	1.00	0.78	1.14
Fe₂O₃	2.76	4.65	7.00	4.29	6.20	3.30	3.87	3.61	4.91
FeO	9.18	10.93	7.60	8.40	9.75	7.85	8.00	8.30	8.85
CaO	9.97	8.10	12.86	8.74	7.66	10.16	8.31	10.67	9.36
MgO	7.00	5.61	3.47	8.11	4.71	7.87	7.05	7.36	6.25
K₂O	0.71	1.33	0.56	1.50	1.45	1.42	1.87	0.56	0.80
Na₂O	1.96	2.65	1.20	2.22	2.14	2.07	1.96	2.12	1.92
MnO	0.20	0.76	0.28	0.23	0.32	0.41	0.36	0.24	0.24
P₂O₅	0.09	0.14	0.14	0.09	0.21	0.10	0.16	0.09	0.13
H₂O⁺	1.66	1.75	2.02	2.92	2.54	2.59	3.00	2.58	2.90
H₂O^-	0.20	0.25	0.08	-	0.26	0.19	0.33	0.23	0.44
灼失量	2.48	2.51	1.46	2.22	1.75	1.92	2.23	1.92	1.97
Rb	53.50	65.50	28.28	89.83	47.98	42.37	109.28	12.29	44.60
Ba	19.74	66.21	9.21	36.10	58.85	86.55	73.38	32.64	32.86
Th	9.79	8.13	10.36	17.56	20.60	7.36	11.44	6.00	9.64
U	8.56	7.19	17.27	13.96	19.56	8.08	7.68	9.41	14.14
Nb	5.25	6.81	7.92	7.42	9.24	3.31	5.15	3.16	7.29
Ta	7.60	13.18	11.65	12.32	17.53	8.37	7.94	8.21	11.39
La	8.35	10.08	11.42	8.17	18.44	6.37	13.94	9.54	10.57
Ce	7.73	9.03	10.13	7.93	14.56	5.22	10.80	7.22	8.52
Pr	7.49	9.14	10.77	7.87	14.09	5.46	10.24	6.73	8.62
Sr	5.89	8.42	9.77	8.75	8.60	15.89	11.98	8.48	7.07
Nd	7.03	8.58	10.91	7.67	12.42	5.09	8.96	5.84	7.80
Zr	7.68	7.21	9.33	7.13	10.22	4.55	6.82	4.07	6.36
Hf	12.90	21.56	21.49	15.61	16.93	8.32	11.78	7.32	10.17
Sm	6.20	7.45	10.13	7.01	11.72	5.25	7.63	5.53	7.98
Eu	6.64	7.84	8.68	6.07	9.34	4.80	6.88	5.25	6.94
Gd	5.16	5.74	9.36	5.89	9.64	4.67	5.78	4.68	6.69
Dy	6.38	6.97	9.40	5.50	9.16	4.53	5.06	4.47	6.54
Y	4.96	5.56	8.08	4.23	7.74	3.72	4.09	3.56	5.41
Ho	5.87	6.46	9.35	4.93	9.08	4.16	4.62	4.13	6.11
Yb	5.56	5.85	8.77	4.04	7.34	3.70	3.92	3.67	5.49
La	5.41	6.53	7.40	5.30	11.95	4.13	9.03	6.18	6.85
Ce	12.95	15.13	16.97	13.28	24.38	8.75	18.09	12.09	14.27
Pr	1.90	2.32	2.74	2.00	3.58	1.39	2.60	1.71	2.19
Nd	8.79	10.72	13.64	9.58	15.52	6.36	11.20	7.30	9.75
Sm	2.52	3.03	4.11	2.84	4.76	2.13	3.10	2.24	3.24
Eu	1.02	1.21	1.34	0.94	1.44	0.74	1.06	0.81	1.07
Gd	2.81	3.13	5.09	3.20	5.25	2.54	3.15	2.55	3.64
Tb	0.60	0.67	0.94	0.57	0.97	0.47	0.56	0.47	0.69
Dy	4.30	4.70	6.34	3.71	6.17	3.06	3.41	3.01	4.41
Ho	0.87	0.96	1.39	0.73	1.35	0.62	0.69	0.62	0.91
Er	2.31	2.49	4.11	1.88	3.77	1.84	2.04	1.83	2.70
Tm	0.43	0.45	0.62	0.29	0.54	0.27	0.29	0.26	0.39
Yb	2.45	2.58	3.87	1.78	3.24	1.63	1.73	1.62	2.42
Lu	0.34	0.33	0.58	0.26	0.49	0.24	0.27	0.25	0.38
Y	21.32	23.90	34.75	18.20	33.27	16.01	17.58	15.29	23.28
∑REE	68.04	78.14	103.90	64.56	116.70	50.16	74.78	56.22	76.18
LREE/HREE	1.35	1.53	1.18	1.65	1.71	1.33	2.21	1.70	1.43
(La/Yb)_CN	1.49	1.71	1.29	2.01	2.50	1.71	3.53	2.58	1.91
δEu	1.14	1.17	0.87	0.92	0.85	0.94	1.01	1.00	0.92
注：样品均为国土资源部武汉矿产资源监督检测中心测试；其中“-”为未分析.

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表 2 林山岩群斜长角闪片岩样品(D029/84-1) LA-ICP-MS残留核部锆石U-Pb定年结果

Table 2. Sample D029/84-1 LA-ICP-MS U-Pb results of relict cores of the zircon from the plagioclase-amphibole schist of Linshan Group

点号	含量(10^-6)		Th/U	U-Th-Pb同位素比值±1σ			同位素年龄±1σ(Ma)
点号	²³²Th	²³⁸U	Th/U	²⁰⁷Pb/²⁰⁶Pb	²⁰⁷Pb/²³⁵U	²⁰⁶Pb/²³⁸U	²⁰⁷Pb/²⁰⁶Pb	²⁰⁷Pb/²³⁵U	²⁰⁶Pb/²³⁸U
D84-1-04	1.76	18.48	0.10	0.160 0±0.005 0	10.97±0.34	0.480±0.008	2 502.0±52.8	2 521.0±28.8	2 546.0±33.0
D84-1-06	0.42	6.72	0.06	0.190 0±0.008 0	13.49±0.54	0.530±0.010	2 744.0±68.8	2 714.0±38.0	2 736.0±40.2
D84-1-08	1.31	7.25	0.18	0.170 0±0.009 0	11.60±0.55	0.510±0.010	2 554.0±79.5	2 573.0±44.4	2 651.0±42.8
D84-1-09	9.39	67.74	0.14	0.160 0±0.003 0	11.77±0.19	0.520±0.004	2 502.0±27.5	2 586.0±15.0	2 687.0±17.1
D84-1-13	0.10	5.36	0.02	0.170 0±0.008 0	11.77±0.54	0.500±0.011	2 583.0±75.2	2 586.0±43.0	2 622.0±48.4
D84-1-14	35.12	3.80	9.24	0.180 0±0.026 0	11.09±0.70	0.480±0.014	2 627.0±248	2 530.0±58.5	2 543.0±62.0
D84-1-22	8.63	47.68	0.18	0.160 0±0.003 0	11.86±0.25	0.520±0.006	2 506.0±33.3	2 594.0±20.2	2 700.0±25.0
D84-1-24	0.20	16.84	0.01	0.170 0±0.004 0	11.13±0.27	0.490±0.006	2 525.0±42.6	2 534.0±22.7	2 552.0±26.7
D84-1-30	0.09	4.91	0.02	0.180 0±0.015 0	11.79±0.82	0.490±0.015	2 696.0±138.0	2 588.0±65.0	2 592.0±63.0
D84-1-43	9.22	65.30	0.14	0.170 0±0.005 0	11.86±0.35	0.510±0.006	2 521.0±49.0	2 594.0±28.0	2 663.0±26.0

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表 3 林山岩群斜长角闪片岩样品(D029/84-1) LA-ICP-MS变质锆石U-Pb定年结果

Table 3. Sample D029/84-1 LA-ICP-MS U-Pb result of rims of the zircon from the plagioclase-amphibole schist of Linshan Group

点号	含量(10^-6)		Th/U	U-Th-Pb同位素比值±1σ			同位素年龄±1σ(Ma)
点号	²³²Th	²³⁸U	Th/U	²⁰⁷Pb/²⁰⁶Pb	²⁰⁷Pb/²³⁵U	²⁰⁶Pb/²³⁸U	²⁰⁷Pb/²⁰⁶Pb	²⁰⁷Pb/²³⁵U	²⁰⁶Pb/²³⁸U
D84-1-02	0.37	23.91	0.015	0.163 6±0.003 7	11.61±0.26	0.520±0.006	2 494.0±37.7	2 574.0±20.6	2 679.0±25.5
D84-1-10	0	7.91	0.000	0.169 2±0.007 1	11.64±0.43	0.520±0.010	2 550.0±70.4	2 576.0±34.7	2 697.0±42.0
D84-1-12	0.21	26.71	0.008	0.157 9±0.003 7	9.95±0.23	0.460±0.005	2 435.0±39.2	2 430.0±21.4	2 425.0±22.5
D84-1-15	10.16	122.05	0.083	0.162 5±0.002 3	10.28±0.15	0.460±0.003	2 483.0±24.1	2 460.0±13.4	2 426.0±14.2
D84-1-16	2.38	58.70	0.041	0.164 3±0.002 9	11.15±0.20	0.490±0.004	2 502.0±29.6	2 535.0±16.6	2 572.0±18.4
D84-1-17	0.03	13.39	0.002	0.176 4±0.004 9	11.78±0.34	0.490±0.006	2 620.0±46.6	2 587.0±27.2	2 552.0±27.7
D84-1-18	0.15	4.83	0.031	0.163 6±0.009 1	9.96±0.49	0.460±0.010	2 494.0±93.8	2 431.0±45.7	2 444.0±43.2
D84-1-23	0.02	7.74	0.003	0.161 3±0.006 4	11.49±0.42	0.530±0.010	2 469.0±67.6	2 564.0±34.2	2 749.0±40.6
D84-1-25	18.07	151.00	0.120	0.158 2±0.001 9	11.62±0.16	0.530±0.004	2 437.0±20.0	2 574.0±13.0	2 731.0±19.0
D84-1-26	6.44	67.60	0.095	0.155 5±0.002 9	11.49±0.23	0.530±0.006	2 409.0±32.0	2 564.0±19.0	2 753.0±27.0
D84-1-28	0.28	23.80	0.012	0.163 4±0.004 7	10.60±0.31	0.470±0.006	2 492.0±48.0	2 489.0±27.0	2 486.0±25.0
D84-1-29	0.69	25.30	0.027	0.157 9±0.004 7	11.69±0.33	0.540±0.007	2 433.0±50.0	2 580.0±27.0	2 777.0±28.0
D84-1-32	0.16	8.87	0.018	0.155 3±0.008 4	9.74±0.50	0.470±0.008	2 405.0±92.0	2 411.0±48.0	2 464.0±37.0
D84-1-33	0.18	12.80	0.014	0.175 9±0.012 2	11.41±0.76	0.480±0.011	2 617.0±115.0	2 557.0±62.0	2 540.0±46.0
D84-1-34	0.03	21.90	0.001	0.158 3±0.004 7	9.94±0.26	0.460±0.005	2 439.0±50.0	2 429.0±24.0	2 431.0±24.0
D84-1-38	0.24	24.40	0.010	0.167 4±0.006 2	10.98±0.40	0.470±0.007	2 531.0±62.0	2 521.0±34.0	2 493.0±30.0
D84-1-40	0.11	51.10	0.002	0.163 7±0.004 2	11.36±0.29	0.500±0.006	2 495.0±44.0	2 553.0±24.0	2 608.0±25.0
D84-1-44	0.03	28.30	0.001	0.163 2±0.006 4	10.46±0.43	0.460±0.006	2 500.0±66.0	2 476.0±38.0	2 439.0±27.0
D84-1-46	0.82	18.70	0.044	0.166 1±0.006 0	10.71±0.38	0.470±0.006	2 518.0±66.0	2 498.0±33.0	2 470.0±27.0
D84-1-47	0.10	11.10	0.009	0.164 8±0.008 1	9.62±0.48	0.430±0.009	2 505.0±83.0	2 400.0±46.0	2 298.0±39.0
D84-1-48	0.20	16.60	0.012	0.164 5±0.005 8	10.40±0.36	0.460±0.007	2 502.0±59.0	2 471.0±32.0	2 438.0±31.0

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