东昆仑黑海地区加里东期过铝质花岗岩岩石学、地球化学特征及地质意义

施彬; 朱云海; 钟增球; 菅坤坤

doi:10.3799/dqkx.2016.003

东昆仑黑海地区加里东期过铝质花岗岩岩石学、地球化学特征及地质意义

doi: 10.3799/dqkx.2016.003

1.
中国地质大学地球科学学院，湖北武汉 430074
2.
陕西省地质调查中心，陕西西安 710016

基金项目:

青海东昆仑1：5万黑海地区五幅区调项目 1212011086001

青海1：5万中灶火地区四幅区调项目 1212010918012

详细信息

作者简介:
施彬(1980-)，男，博士，从事岩浆岩岩石学及区域地质调查研究.E-mail: 7293026@qq.com

中图分类号: P588.121; P595; P597.3
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出版历程
- 收稿日期: 2015-08-06
- 刊出日期: 2016-01-15

Petrological, Geochemical Characteristics and Geological Significance of the Caledonian Peraluminous Granites in Heihai Region, Eastern Kunlun

1.
Faculty of Earth Sciences, China University of Geosciences, Wuhan 430074, China
2.
Shaanxi Center of Geological Survey, Xi'an 710016, China

摘要

摘要: 东昆仑黑海地区发育加里东期过铝质花岗岩(424.0~420.5 Ma)，其形成与地壳的发展演化密切相关，主要通过岩相学和地球化学方法对其进行了研究.黑海过铝质花岗岩由黑云母英云闪长岩、黑云母花岗闪长岩、黑云母花岗岩、二云母花岗岩和白云母花岗岩组成.SiO₂变化区间为65.32%~75.87%，K₂O/Na₂O为0.47~1.52，δ为1.09~3.00，为钙碱性-高钾钙碱性系列；A/CNK为1.02~1.31，属于过铝质-强过铝质花岗岩.稀土元素具有轻稀土相对富集和重稀土相对亏损的特征，中等负铕异常.微量元素具有相对选择性富集大离子亲石元素而相对亏损高场强元素的特征.源区参与熔融物质由以变杂砂岩为主，向以变泥质岩为主过渡.结合区域资料，认为黑海过铝质花岗岩是东昆南俯冲增生杂岩楔发生伸展减薄引起地幔物质底侵而促使富硅铝地壳物质发生不同程度部分熔融形成.
- 东昆仑造山带 /
- 黑海 /
- 加里东期 /
- 过铝质花岗岩 /
- 岩石学
Abstract: Caledonian peraluminous granites (420.5 to 424.0 Ma), is closely related with the development and evolution of the crust. In order to study their composition features and formation mechchanism, petrographical and geochemical investigations were carried out. It consist of biotite tonalite, biotite granodiorite, biotite granite, two-mica granite and muscovite granite in Heihai region. The rock types are of calc-alkali series and high-K calc-alkaline series (SiO₂=65.32%-75.87%, K₂O/Na₂O=0.47-1.52, δ=1.09-3.00), and belong to peraluminous granites or strongly peraluminous granites (A/CNK=1.02-1.31). REE display relatively LREE-enriched and HREE-depleted characteristics, with moderate Eu negative abnormality. LILE are of relatively selective enrichment and HFS elements are of relatively depletion. The melting materials of source are metagreywacke and metapelite. Based on regional geology, this paper suggests that Heihai peraluminous granites were formed by partial melting of the alumina-silica crust, which was caused by mantle underplating and extension of the southern subduction accretionary complex.
- eastern Kunlun orogenic belt /
- Heihai region /
- caledonian /
- peraluminous granite /
- petrology

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图 1 东昆仑造山带构造单元划分

Ⅰ.东昆北岩浆弧；Ⅱ.东昆北蛇绿构造混杂岩带；Ⅲ.东昆中复合岩浆弧；Ⅳ.东昆中蛇绿构造混杂岩带；Ⅴ.东昆南俯冲增生杂岩楔；Ⅵ.东昆南蛇绿构造混杂岩带

Fig. 1. Tectonic unit map of the eastern Kunlun orogenic belt

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图 2 黑海地区地质简图

1.第四纪；2.三叠纪地层；3.石炭-二叠纪浩特洛哇组；4.志留纪赛什腾组；5.奥陶-志留纪纳赤台群；6.中元古代万宝沟群；7.三叠纪花岗岩；8.晚三叠世辉长岩；9.晚志留世过铝质花岗岩(研究对象)；10.区域断裂；11.地质界线；12.角度不整合界线

Fig. 2. Simplified geological map of the Heihai region

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图 3 黑海地区加里东期过铝质花岗岩野外露头及显微镜下特征

a.晚志留世过铝质花岗岩(γS₃)与赛什腾组(Ss)侵入接触；b.含石榴子石白云母花岗岩(Mu.白云母，Gt.石榴子石)；c.白云母花岗岩(γm)与黑云母花岗岩(γβ)侵入接触；d.花岗闪长岩(γδ)中的似斑状英云闪长岩(πγδο)包体；e.石榴子石(Gt)显微镜下特征(单偏光)；f.石榴子石(Gt)显微镜下特征(正交光)

Fig. 3. Macroscopic and microcosmic characteristics of the caledonian peraluminous granites in Heihai region

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图 4 主量元素图解

a.AR-SiO₂图解，据邓晋福等(2004)；b.SiO₂-K₂O图解，据Rickwood(1989)；c.A/CNK-A/NK图解，据Maniar and Piccoli(1989)；d.SiO₂-FeO/(FeO+MgO)图解, 据Frost et al.(2001)；图中叉形代表英云闪长岩，三角形代表花岗闪长岩，菱形代表黑云母花岗岩，圆形代表二云母花岗岩，正方形代表白云母花岗岩，后续图相同

Fig. 4. Major elements diagrams

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图 5 黑海地区过铝质花岗岩稀土元素球粒陨石标准化曲线

黑色代表英云闪长岩，紫色代表花岗闪长岩，蓝色代表黑云母花岗岩，绿色代表二云母花岗岩，红色代表白云母花岗岩；球粒陨石标准化值据Taylor and Mclennan(1985)

Fig. 5. Chondrite-normalized REE distribution patterns of the peraluminous granites in Heihai region

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图 6 黑海地区过铝质花岗岩微量元素原始地幔标准化曲线

黑色代表英云闪长岩，紫色代表花岗闪长岩，蓝色代表黑云母花岗岩，绿色代表二云母花岗岩，红色代表白云母花岗岩；原始地幔标准化值据McDonough et al.(1992)

Fig. 6. Primitive mantle-normalized patterns of the peraluminous granites in Heihai region

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图 7 黑海地区过铝质花岗岩源区特征图解

a.SiO₂-T_Zr图解；b.Yb-Sr图解(据张旗等, 2006)；c.Rb/Sr-Rb/Ba关系图解，据Sylvester(1998)；d.Al₂O₃/TiO₂-CaO/Na₂O，据Sylvester(1998)；Ⅰ.高Sr低Yb型，Ⅱ.低Sr低Yb型，Ⅲ.高Sr高Yb型，Ⅳ.低Sr高Yb型，Ⅴ.非常低Sr高Yb型

Fig. 7. Source characteristics of the peraluminous granites in Heihai region

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表 1 黑海地区过铝质花岗岩主量元素测试结果及特征值

Table 1. Analysis results and eigenvalues of major elements of the peraluminous granites in Heihai region

序号	样品号	SiO₂	TiO₂	Al₂O₃	Fe₂O₃	FeO	MnO	MgO	CaO	Na₂O	K₂O	P₂O₅	H₂O⁺	CO₂	∑	ALK	K₂O/Na₂O	σ	AR	A/CNK	Norm.C
1	02-1-1	70.26	0.39	14.84	0.32	2.08	0.05	0.86	2.25	3.41	4.00	0.14	1.06	0.06	99.72	7.41	1.17	2.01	2.39	1.07	1.28
2	02-3-1	71.35	0.37	14.29	0.99	1.17	0.04	0.77	2.10	3.31	4.30	0.13	0.83	0.10	99.75	7.61	1.30	2.04	2.46	1.04	0.92
3	02-4-1	73.75	0.27	13.49	0.49	1.07	0.03	0.59	1.66	3.15	4.26	0.10	0.81	0.10	99.77	7.41	1.35	1.79	2.55	1.06	1.15
4	02-7-1	71.59	0.38	14.30	0.62	1.67	0.05	0.80	2.30	3.52	3.38	0.15	0.81	0.16	99.73	6.90	0.96	1.67	2.42	1.06	1.40
5	02-8-1	72.98	0.28	14.21	0.44	1.27	0.04	0.58	1.70	3.93	3.51	0.09	0.71	0.04	99.78	7.44	0.89	1.85	2.76	1.07	1.16
6	02-9-1	72.32	0.30	14.28	0.24	1.53	0.04	0.61	1.84	3.58	4.02	0.11	0.82	0.04	99.73	7.60	1.12	1.97	2.65	1.06	1.05
7	02-10-1	72.03	0.28	14.25	0.33	1.37	0.04	0.55	1.96	3.38	4.51	0.10	0.82	0.12	99.74	7.89	1.33	2.14	2.55	1.03	0.76
8	02-11-1	71.87	0.36	14.00	0.51	1.67	0.04	0.81	2.15	3.42	3.65	0.14	1.00	0.12	99.74	7.07	1.07	1.73	2.49	1.05	1.13
9	02-13-1	71.86	0.39	14.23	0.40	1.80	0.05	0.84	2.00	3.52	3.50	0.15	0.96	0.06	99.76	7.02	0.99	1.71	2.52	1.09	1.51
10	02-15-1	71.13	0.42	14.76	0.95	1.63	0.07	0.89	2.09	4.27	2.31	0.18	0.94	0.10	99.74	6.58	0.54	1.54	2.28	1.13	2.10
11	02-17-1	71.10	0.38	14.71	0.68	1.60	0.04	0.83	1.97	3.37	3.87	0.13	0.98	0.10	99.76	7.24	1.15	1.87	2.41	1.12	1.94
12	02-18-1	70.03	0.42	15.20	0.46	1.87	0.04	0.92	2.46	3.61	3.49	0.14	1.01	0.08	99.73	7.10	0.97	1.86	2.34	1.08	1.53
13	13-6-1	72.43	0.29	14.28	0.55	1.32	0.04	0.69	2.17	3.61	3.24	0.12	0.86	0.13	99.73	6.85	0.90	1.59	2.43	1.08	1.48
14	13-7-1	72.44	0.30	14.36	0.39	1.45	0.04	0.67	1.97	3.54	3.42	0.11	0.72	0.09	99.50	6.96	0.97	1.65	2.49	1.11	1.72
15	13-8-1	72.24	0.28	14.58	0.61	1.13	0.04	0.63	1.89	3.58	3.59	0.10	0.82	0.11	99.60	7.17	1.00	1.76	2.54	1.11	1.86
16	13-9-1	72.64	0.26	14.53	0.38	1.30	0.04	0.62	1.72	3.61	3.46	0.10	0.89	0.06	99.61	7.07	0.96	1.69	2.54	1.14	2.10
17	13-10-1	73.56	0.28	13.81	0.49	1.23	0.04	0.61	2.04	3.31	3.52	0.11	0.73	0.09	99.82	6.83	1.06	1.53	2.46	1.08	1.32
18	13-11-1	72.03	0.30	14.68	0.61	1.27	0.04	0.70	2.10	3.45	3.62	0.11	0.88	0.04	99.83	7.07	1.05	1.72	2.41	1.11	1.62
19	13-12-1	72.03	0.28	14.56	0.67	1.13	0.04	0.66	2.51	3.68	3.25	0.11	0.76	0.13	99.81	6.93	0.88	1.65	2.37	1.04	0.99
20	02-20-1	71.01	0.41	14.74	0.57	1.77	0.04	0.89	2.48	3.63	3.26	0.15	0.66	0.12	99.73	6.89	0.90	1.69	2.33	1.07	1.37
21	02-21-1	70.51	0.42	14.42	0.60	1.73	0.05	1.03	1.38	3.67	4.52	0.14	1.16	0.08	99.71	8.19	1.23	2.44	2.84	1.09	1.50
22	09-3-1	72.37	0.21	14.02	0.26	1.13	0.02	0.55	0.80	2.33	7.06	0.22	0.78	0.04	99.79	9.39	3.03	3.00	2.38	1.11	1.71
23	09-4-1	72.42	0.30	14.60	0.39	1.52	0.04	0.80	0.82	3.22	4.20	0.19	1.30	0.04	99.84	7.42	1.30	1.87	2.54	1.31	3.81
24	09-6-1	71.76	0.24	15.28	0.42	1.17	0.04	0.58	0.82	4.07	4.08	0.18	1.10	0.13	99.87	8.15	1.00	2.31	3.05	1.23	3.41
25	09-7-1	71.83	0.33	14.83	0.51	1.60	0.04	0.78	1.37	3.27	3.65	0.18	1.37	0.06	99.82	6.92	1.12	1.66	2.39	1.28	3.58
26	09-9-1	70.10	0.57	14.11	0.86	2.67	0.06	1.25	1.35	2.43	4.81	0.27	1.31	0.04	99.83	7.24	1.98	1.93	2.14	1.24	3.19
27	09-10-1	73.09	0.22	14.25	0.36	1.22	0.04	0.56	1.27	3.09	4.37	0.22	1.03	0.11	99.83	7.46	1.41	1.85	2.46	1.20	2.91
28	12-2-1	74.84	0.11	13.77	0.39	0.75	0.04	0.36	0.52	3.38	4.52	0.15	0.82	0.21	99.86	7.90	1.34	1.96	2.95	1.23	3.22
29	12-3-1	74.61	0.12	13.89	0.40	0.80	0.05	0.44	0.61	3.44	4.56	0.17	0.67	0.08	99.84	8.00	1.33	2.02	2.95	1.21	2.78
30	12-4-1	73.93	0.18	13.98	0.47	1.03	0.03	0.55	0.68	3.09	4.86	0.19	0.82	0.02	99.83	7.95	1.57	2.04	2.67	1.23	2.90
31	12-5-1	73.00	0.23	14.07	0.60	1.12	0.04	0.63	1.04	2.89	4.99	0.26	0.92	0.06	99.85	7.88	1.73	2.07	2.46	1.20	2.78
32	12-6-1	73.24	0.22	14.20	0.43	1.15	0.03	0.55	0.69	2.92	4.83	0.27	1.17	0.17	99.87	7.75	1.65	1.99	2.50	1.30	3.95
33	12-7-1	74.93	0.10	14.11	0.49	0.50	0.04	0.31	0.48	3.57	4.36	0.17	0.75	0.06	99.87	7.93	1.22	1.97	3.02	1.25	3.19
34	12-8-1	74.60	0.16	13.72	0.46	0.92	0.03	0.46	0.78	3.08	4.36	0.18	0.88	0.19	99.82	7.44	1.42	1.75	2.63	1.25	3.39
35	12-9-1	73.04	0.23	14.35	0.31	1.30	0.03	0.63	0.84	2.86	4.97	0.28	0.85	0.15	99.84	7.83	1.74	2.04	2.43	1.27	3.76
36	12-10-1	72.46	0.20	13.50	0.24	1.27	0.05	1.04	1.55	2.83	4.49	0.23	1.18	0.81	99.85	7.32	1.59	1.82	2.38	1.12	3.59
37	12-11-1	73.16	0.23	14.28	0.38	1.25	0.03	0.66	0.72	2.86	4.92	0.27	1.00	0.09	99.85	7.78	1.72	2.01	2.45	1.30	3.80
38	12-13-1	72.57	0.23	14.32	0.54	1.30	0.04	0.77	0.67	2.25	5.58	0.32	1.18	0.06	99.83	7.83	2.48	2.07	2.18	1.35	4.27
39	12-14-1	70.24	0.31	15.32	0.64	1.73	0.05	1.00	2.42	3.67	3.09	0.27	1.02	0.11	99.87	6.76	0.84	1.68	2.23	1.14	2.44
40	13-1-1	73.66	0.22	13.84	0.09	1.12	0.02	0.43	0.80	3.03	5.35	0.25	1.01	0.04	99.86	8.38	1.77	2.29	2.68	1.16	2.30
41	13-2-1	72.96	0.23	14.44	0.26	1.20	0.03	0.46	1.11	2.94	4.91	0.24	1.02	0.04	99.84	7.85	1.67	2.06	2.42	1.22	2.94
42	13-3-1	73.61	0.22	13.82	0.41	1.07	0.03	0.45	1.09	2.82	4.96	0.25	0.85	0.11	99.69	7.78	1.76	1.98	2.45	1.18	2.68
43	13-4-1	73.38	0.21	14.07	0.60	0.82	0.03	0.46	1.06	2.92	5.03	0.23	0.88	0.06	99.75	7.95	1.72	2.08	2.48	1.18	2.58
44	13-13-1	72.25	0.29	14.51	0.52	1.30	0.05	0.65	1.85	3.61	3.52	0.12	1.04	0.09	99.80	7.13	0.98	1.74	2.54	1.12	1.89
45	13-15-1	72.56	0.22	14.70	0.23	1.17	0.04	0.42	1.39	3.74	4.15	0.17	0.85	0.11	99.75	7.89	1.11	2.11	2.79	1.13	2.19
46	13-16-1	72.82	0.20	14.49	0.40	0.98	0.04	0.42	1.11	3.72	4.09	0.17	1.06	0.09	99.59	7.81	1.10	2.05	2.87	1.17	2.54
47	02-12-1	75.90	0.05	13.59	0.03	0.48	0.02	0.10	0.46	3.47	4.92	0.16	0.64	0.10	99.92	8.39	1.42	2.14	3.16	1.16	2.54
48	02-19-1	75.70	0.03	13.69	0.08	0.32	0.03	0.08	0.79	4.08	4.02	0.22	0.64	0.14	99.82	8.10	0.99	2.01	3.54	1.12	2.04
49	13-5-1	73.99	0.14	14.59	0.52	0.53	0.02	0.18	0.85	3.46	4.29	0.21	0.96	0.13	99.87	7.75	1.24	1.94	2.72	1.25	3.51
50	13-14-1	73.09	0.13	14.98	0.38	0.63	0.04	0.27	1.20	3.92	4.18	0.17	0.72	0.15	99.86	8.10	1.07	2.18	2.91	1.16	2.58
51	13-17-1	74.94	0.10	14.16	0.20	0.67	0.04	0.22	0.96	3.26	3.94	0.28	0.95	0.09	99.81	7.20	1.21	1.62	2.60	1.28	3.67
52	09-1-1	67.00	0.91	13.85	1.28	4.38	0.11	2.07	2.54	2.28	2.84	0.34	2.19	0.04	99.83	5.12	1.25	1.09	1.82	1.26	3.31
53	09-3-2	66.87	0.87	14.20	1.35	4.12	0.07	2.02	2.24	2.50	3.38	0.32	1.83	0.04	99.81	5.88	1.35	1.45	1.95	1.24	3.21
54	09-5-1	64.88	0.94	14.85	1.27	4.57	0.10	2.06	2.59	2.63	4.00	0.35	1.46	0.08	99.78	6.63	1.52	2.01	1.98	1.15	2.51
55	09-8-1	68.95	0.67	14.08	1.02	3.08	0.07	1.62	1.25	3.40	3.53	0.34	1.74	0.08	99.83	6.93	1.04	1.85	2.61	1.25	3.39
56	02-5-1	65.32	0.71	16.44	0.89	3.42	0.12	1.62	2.55	4.46	2.11	0.24	1.79	0.10	99.77	6.57	0.47	1.93	2.06	1.18	2.99
注：含量单位为%；1~19样品为黑云母花岗岩；20~46样品为二云母花岗岩；47~51样品为白云母花岗岩；52~55样品为黑云母花岗岩闪长岩；56样品为黑云母英云闪长岩.

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表 2 黑海地区过铝质花岗岩稀土元素测试结果及特征值

Table 2. Analysis results and eigenvalues of rare earth elements of the peraluminous granites in Heihai region

序号	样品号	La	Ce	Pr	Nd	Sm	Eu	Gd	Tb	Dy	Ho	Er	Tm	Yb	Lu	Y	总量	La_N/Yb_N	δEu
1	02-1-1	45.73	86.43	9.47	31.23	5.12	1.00	4.22	0.61	2.91	0.51	1.38	0.21	1.20	0.18	14.89	205.10	0.63	0.16
2	02-3-1	47.13	88.95	9.92	32.99	5.28	0.96	4.29	0.60	2.79	0.48	1.19	0.19	0.98	0.16	13.37	209.27	0.92	0.16
3	02-4-1	39.18	73.74	8.37	27.80	5.07	0.81	4.02	0.55	2.41	0.39	0.97	0.16	0.75	0.13	10.97	175.30	0.94	0.14
4	02-7-1	55.86	103.50	11.33	36.31	5.62	1.04	4.29	0.58	2.57	0.43	1.23	0.20	1.20	0.19	12.64	237.00	0.87	0.26
5	02-8-1	39.26	74.69	8.35	28.15	5.24	0.78	4.87	0.78	4.38	0.82	2.39	0.37	2.39	0.34	25.55	198.36	1.47	0.20
6	02-9-1	43.74	80.84	8.77	28.70	4.39	0.89	3.58	0.49	2.11	0.36	0.98	0.16	0.82	0.14	10.83	186.80	1.07	0.15
7	02-10-1	36.19	65.93	7.37	23.87	3.80	0.85	2.91	0.42	1.73	0.29	0.72	0.13	0.65	0.11	8.18	153.14	1.38	0.19
8	02-11-1	41.54	78.10	8.86	29.81	5.10	0.93	4.18	0.59	2.78	0.49	1.32	0.21	1.17	0.19	14.39	189.66	0.78	0.21
9	02-13-1	41.15	77.95	8.59	27.86	4.57	0.92	3.64	0.53	2.41	0.40	1.08	0.17	0.94	0.15	11.50	181.86	0.72	0.19
10	02-15-1	61.84	113.20	12.40	41.03	6.57	1.03	5.37	0.75	3.36	0.55	1.37	0.21	1.07	0.17	15.17	264.07	0.90	0.16
11	02-17-1	45.41	86.25	9.52	31.43	5.27	0.96	4.38	0.58	2.65	0.46	1.16	0.19	1.04	0.16	12.96	202.41	0.79	0.17
12	02-18-1	52.47	97.44	10.78	35.38	5.44	1.20	4.06	0.55	2.54	0.42	1.15	0.17	0.87	0.15	12.18	224.80	0.68	0.15
13	13-6-1	32.27	59.63	6.57	23.19	4.19	0.81	3.32	0.49	2.52	0.43	1.15	0.17	1.09	0.16	11.85	147.84	0.71	0.21
14	13-7-1	33.15	61.77	6.84	23.70	4.23	0.81	3.44	0.51	2.49	0.42	1.10	0.17	0.96	0.15	11.64	151.38	0.76	0.17
15	13-8-1	31.59	59.07	6.60	23.36	4.16	0.81	3.43	0.51	2.68	0.47	1.21	0.18	1.12	0.16	12.62	147.97	0.87	0.20
16	13-9-1	30.92	58.47	6.55	23.27	4.24	0.80	3.48	0.53	2.71	0.48	1.27	0.19	1.26	0.18	12.98	147.32	0.74	0.17
17	13-10-1	23.17	43.35	4.89	17.41	3.30	0.74	2.90	0.44	2.43	0.45	1.24	0.19	1.20	0.18	12.53	114.41	0.93	0.19
18	13-11-1	33.26	62.06	6.92	24.13	4.38	0.79	3.51	0.54	2.87	0.50	1.32	0.19	1.20	0.17	12.65	154.49	0.80	0.18
19	13-12-1	38.70	72.82	8.10	28.33	5.03	0.84	3.95	0.60	3.14	0.55	1.49	0.23	1.52	0.21	15.49	181.01	0.83	0.19
20	02-20-1	50.63	96.71	10.43	34.46	5.51	0.99	4.33	0.57	2.62	0.42	1.18	0.17	0.93	0.15	12.31	221.41	0.65	0.18
21	02-21-1	49.62	98.46	11.14	35.76	5.35	1.10	3.82	0.51	2.11	0.35	0.96	0.15	0.82	0.14	10.25	220.55	0.90	0.14
22	09-3-1	25.30	51.05	6.39	23.05	5.46	1.23	4.84	0.76	4.21	0.73	2.29	0.31	2.06	0.30	34.52	162.51	1.26	0.17
23	09-4-1	24.62	49.03	5.99	21.78	4.60	0.74	3.66	0.58	3.05	0.55	1.68	0.23	1.48	0.22	25.01	143.22	1.18	0.22
24	09-6-1	22.98	42.94	5.26	19.15	3.90	0.76	3.32	0.54	2.92	0.57	1.76	0.24	1.45	0.21	26.61	132.60	0.97	0.25
25	09-7-1	27.21	51.96	6.44	23.24	4.91	0.87	3.94	0.62	3.32	0.60	1.64	0.25	1.54	0.23	18.34	145.11	1.27	0.20
26	09-9-1	37.65	76.13	9.53	36.22	7.87	1.15	6.67	1.09	6.38	1.20	3.39	0.48	3.04	0.41	31.83	223.04	1.15	0.14
27	09-10-1	20.99	41.33	5.11	18.60	4.12	0.62	3.48	0.54	2.96	0.52	1.63	0.22	1.37	0.19	24.84	126.51	1.84	0.26
28	12-2-1	12.36	25.19	3.25	11.72	2.95	0.40	2.55	0.47	2.61	0.49	1.35	0.19	1.26	0.18	18.98	83.94	3.08	0.25
29	12-3-1	15.57	32.05	4.17	15.12	3.61	0.54	3.11	0.53	2.96	0.54	1.63	0.23	1.45	0.21	23.29	104.99	2.93	0.31
30	12-4-1	23.51	48.61	6.28	22.88	5.23	0.67	4.18	0.67	3.54	0.63	1.81	0.23	1.45	0.21	16.37	136.26	1.84	0.18
31	12-5-1	26.78	54.62	7.19	26.37	6.05	0.72	5.04	0.78	3.78	0.64	1.73	0.22	1.34	0.19	23.10	158.53	1.74	0.17
32	12-6-1	25.60	52.62	6.59	24.38	5.37	0.64	4.60	0.69	3.52	0.59	1.59	0.21	1.26	0.17	24.73	152.56	1.66	0.18
33	12-7-1	10.07	20.07	2.63	9.39	2.23	0.37	1.99	0.35	2.08	0.38	1.28	0.19	1.26	0.18	22.18	74.65	2.53	0.45
34	12-8-1	19.09	38.48	5.10	18.71	4.26	0.60	3.46	0.56	2.91	0.51	1.61	0.20	1.26	0.17	25.11	122.04	1.66	0.22
35	12-9-1	27.58	56.57	7.34	27.09	5.99	0.74	4.89	0.77	3.88	0.63	1.63	0.21	1.28	0.17	22.16	160.93	1.76	0.15
36	12-10-1	24.18	49.07	6.39	23.73	5.42	0.64	4.44	0.70	3.53	0.61	1.72	0.21	1.33	0.18	25.49	147.64	1.33	0.16
37	12-11-1	26.25	53.56	6.91	25.27	5.67	0.70	4.60	0.71	3.33	0.53	1.50	0.18	1.08	0.16	20.80	151.26	1.68	0.18
38	12-13-1	21.29	52.42	5.61	21.61	5.08	0.65	4.10	0.62	2.91	0.47	1.41	0.17	0.93	0.13	24.86	142.26	1.57	0.15
39	12-14-1	17.92	35.99	4.80	17.58	3.86	0.74	3.29	0.49	2.28	0.39	1.01	0.14	0.90	0.13	10.95	100.46	1.59	0.24
40	13-1-1	26.94	55.94	6.67	25.11	5.30	0.63	4.24	0.61	2.73	0.40	0.96	0.14	0.82	0.11	10.50	141.10	2.00	0.17
41	13-2-1	29.75	60.92	7.24	26.96	5.71	0.65	4.51	0.68	3.10	0.46	1.13	0.18	1.00	0.13	11.73	154.15	1.91	0.16
42	13-3-1	28.42	57.34	6.95	25.75	5.79	0.61	4.59	0.77	3.69	0.57	1.37	0.20	1.29	0.16	12.84	150.34	1.87	0.16
43	13-4-1	25.47	52.20	6.10	22.40	4.79	0.60	3.92	0.60	2.63	0.42	1.01	0.14	0.86	0.11	11.17	132.41	1.68	0.17
44	13-13-1	31.54	58.90	6.59	23.18	4.16	0.79	3.31	0.49	2.45	0.42	1.07	0.16	0.98	0.14	11.01	145.18	1.12	0.19
45	13-15-1	24.19	45.90	5.35	19.22	3.91	0.68	3.28	0.59	3.29	0.56	1.54	0.25	1.58	0.21	15.86	126.42	2.05	0.23
46	13-16-1	22.48	43.56	4.94	17.56	3.45	0.66	2.75	0.46	2.38	0.41	1.06	0.16	1.03	0.15	11.45	112.51	1.37	0.29
47	02-12-1	4.08	7.34	0.89	3.04	0.77	0.33	0.89	0.23	1.20	0.24	0.68	0.14	0.76	0.13	7.92	28.64	9.40	0.23
48	02-19-1	5.65	10.85	1.21	3.97	1.04	0.36	1.13	0.28	1.35	0.23	0.58	0.11	0.54	0.10	7.24	34.64	5.15	0.43
49	13-5-1	14.86	31.25	3.57	13.36	2.87	0.45	2.73	0.46	2.38	0.40	1.02	0.16	0.91	0.13	11.36	85.92	2.54	0.28
50	13-14-1	14.18	26.70	3.20	11.54	2.71	0.39	2.39	0.48	2.60	0.44	1.19	0.21	1.31	0.17	11.38	78.90	3.03	0.23
51	13-17-1	10.08	19.78	2.25	8.04	1.89	0.32	1.76	0.36	2.08	0.37	1.06	0.18	1.09	0.15	11.00	60.39	3.72	0.44
52	09-1-1	48.61	97.96	12.55	47.98	10.18	1.60	9.16	1.54	8.88	1.62	4.25	0.56	3.29	0.46	44.17	292.80	0.48	0.17
53	09-3-2	47.37	95.00	11.95	46.32	9.32	1.52	7.87	1.23	6.42	1.11	2.76	0.42	2.72	0.40	32.20	266.59	0.67	0.15
54	09-5-1	43.13	85.45	10.56	40.46	8.92	1.60	7.88	1.37	8.26	1.63	4.63	0.69	4.39	0.60	45.31	264.89	0.83	0.14
55	09-8-1	33.95	68.92	8.56	32.29	6.93	1.30	5.89	0.94	4.86	0.84	2.06	0.24	1.44	0.22	27.16	195.60	0.61	0.21
56	02-5-1	134.60	244.10	26.63	85.16	13.49	1.20	10.42	1.46	7.03	1.16	2.99	0.40	2.32	0.32	33.49	564.78	0.45	0.16
	09-1-2	46.54	96.23	12.05	46.45	10.07	1.50	9.18	1.44	8.30	1.45	3.36	0.39	1.97	0.25	41.78	280.95	0.61	0.15
注：含量单位为10^-6；1~19样品为黑云母花岗岩；20~46样品为二云母花岗岩；47~51样品为白云母花岗岩；52~55样品为黑云母花岗岩闪长岩；56样品为黑云母英云闪长岩.

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表 3 黑海地区过铝质花岗岩微量元素测试结果及特征值

Table 3. Analysis results and eigenvalues of trace elements of the peraluminous granites in Heihai region

序号	样品号	Cs	Rb	Ba	Th	U	Ta	Nb	Sr	Hf	Zr	Rb/Sr	Rb/Ba	T_Zr
1	02-1-1	8.43	137.55	1 145.00	18.47	1.68	1.46	13.83	261.60	7.31	219.40	0.53	0.12	788.64
2	02-3-1	8.66	186.28	969.20	21.82	1.13	1.40	13.06	231.80	6.07	202.20	0.80	0.19	790.92
3	02-4-1	6.32	134.11	602.00	21.30	1.33	1.09	10.84	199.60	4.77	143.00	0.67	0.22	789.94
4	02-7-1	14.18	189.63	900.80	15.19	0.97	1.93	11.60	264.30	6.88	218.00	0.72	0.21	792.45
5	02-8-1	12.77	218.27	543.20	21.22	2.18	1.70	13.66	168.90	4.96	148.90	1.29	0.40	783.33
6	02-9-1	5.80	174.28	1 056.00	16.46	0.91	1.17	11.48	260.10	5.36	162.70	0.67	0.17	788.14
7	02-10-1	8.53	195.39	929.60	16.04	0.94	1.35	9.69	243.20	4.71	141.20	0.80	0.21	788.42
8	02-11-1	7.97	161.54	811.20	27.35	1.72	1.86	13.70	261.10	6.15	206.30	0.62	0.20	812.95
9	02-13-1	7.48	152.06	799.50	17.06	1.23	1.22	9.50	248.90	5.97	211.50	0.61	0.19	803.90
10	02-15-1	22.61	213.90	728.10	26.86	1.40	1.28	13.28	224.90	7.27	237.50	0.95	0.29	779.66
11	02-17-1	9.31	163.22	796.10	22.65	1.74	1.25	11.21	261.10	5.68	207.40	0.63	0.21	813.55
12	02-18-1	13.53	160.89	1 014.00	16.10	0.72	0.95	9.54	314.70	6.68	236.20	0.51	0.16	782.39
13	13-6-1	11.87	114.31	576.10	14.44	1.19	1.36	9.84	161.30	5.37	159.90	0.71	0.20	788.24
14	13-7-1	12.84	120.14	606.10	16.04	1.15	1.06	9.38	161.10	4.93	159.00	0.75	0.20	772.39
15	13-8-1	13.73	135.80	647.90	14.56	1.08	1.31	9.67	170.90	5.63	156.60	0.79	0.21	807.98
16	13-9-1	14.03	115.65	642.20	15.65	1.45	1.01	8.60	164.80	5.22	155.40	0.70	0.18	813.96
17	13-10-1	9.86	137.81	606.00	13.31	1.39	1.24	9.63	146.20	4.76	147.90	0.94	0.23	826.33
18	13-11-1	13.40	124.72	629.75	12.91	1.11	1.17	9.54	169.00	5.97	155.60	0.74	0.20	813.79
19	13-12-1	13.38	138.76	578.65	16.51	1.46	1.25	9.74	174.20	5.49	167.90	0.80	0.24	820.60
20	02-20-1	12.68	144.62	822.80	19.57	0.98	1.16	9.94	299.90	6.53	224.10	0.48	0.18	775.60
21	02-21-1	5.07	193.53	1 295.00	16.08	0.97	0.92	9.14	252.70	5.88	215.30	0.77	0.15	785.29
22	09-3-1	5.18	191.50	839.40	16.83	2.80	1.25	7.71	161.30	4.47	152.20	1.19	0.23	781.97
23	09-4-1	5.88	201.80	546.60	13.90	2.88	1.70	11.13	121.30	4.79	170.30	1.66	0.37	777.40
24	09-6-1	9.60	141.20	485.70	6.20	0.86	1.82	10.67	71.07	4.10	145.00	1.99	0.29	786.66
25	09-7-1	6.72	194.20	567.10	15.68	2.51	1.46	11.12	148.50	4.40	152.40	1.31	0.34	761.53
26	09-9-1	13.77	269.70	643.30	24.79	3.17	1.59	17.16	110.60	6.58	235.20	2.44	0.42	770.42
27	09-10-1	18.51	251.20	437.50	13.00	1.84	2.16	11.97	94.20	3.92	136.80	2.67	0.57	755.01
28	12-2-1	18.57	280.10	276.80	8.09	2.03	2.22	13.31	51.29	2.90	90.90	5.46	1.01	764.04
29	12-3-1	19.99	304.70	342.70	10.81	3.03	2.67	12.89	71.40	3.20	103.90	4.27	0.89	786.77
30	12-4-1	12.73	246.80	482.40	14.79	2.40	1.58	12.46	91.37	4.11	134.10	2.70	0.51	786.13
31	12-5-1	11.86	242.20	463.60	14.68	2.14	1.71	14.67	78.13	4.37	139.10	3.10	0.52	790.25
32	12-6-1	7.09	223.20	447.50	15.14	2.16	1.85	15.53	69.65	4.00	134.40	3.20	0.50	760.78
33	12-7-1	18.26	243.30	251.50	4.78	2.24	2.51	6.84	41.73	2.80	95.99	5.83	0.97	783.71
34	12-8-1	9.22	209.50	446.10	11.14	2.30	1.83	11.89	80.32	3.75	126.00	2.61	0.47	791.38
35	12-9-1	8.63	245.10	483.80	18.58	1.96	1.63	16.20	91.21	4.28	139.40	2.69	0.51	777.41
36	12-10-1	3.94	179.50	444.50	14.15	0.94	1.52	14.22	84.57	4.10	134.60	2.12	0.40	793.18
37	12-11-1	10.40	233.60	481.10	15.73	2.33	1.81	15.07	83.42	4.21	139.30	2.80	0.49	806.94
38	12-13-1	9.49	246.90	451.90	14.09	2.22	1.69	17.44	104.90	4.78	157.30	2.35	0.55	769.45
39	12-14-1	14.75	201.40	216.60	11.78	1.92	2.04	13.68	133.40	3.67	126.60	1.51	0.93	785.87
40	13-1-1	7.24	252.41	402.90	16.71	2.73	1.72	15.18	83.80	4.30	126.30	3.01	0.63	812.37
41	13-2-1	13.34	259.19	419.80	18.64	2.11	1.52	14.11	90.00	4.37	135.60	2.88	0.62	790.88
42	13-3-1	8.97	248.01	378.95	16.17	2.37	1.67	15.75	87.80	4.34	132.90	2.82	0.65	799.49
43	13-4-1	12.00	212.87	352.90	13.30	2.50	1.69	14.58	86.60	4.21	126.40	2.46	0.60	834.54
44	13-13-1	17.08	168.75	638.90	16.21	1.38	1.28	10.05	156.00	5.43	150.30	1.08	0.26	785.46
45	13-15-1	20.63	226.72	579.25	10.32	1.69	1.86	12.34	137.40	4.01	110.80	1.65	0.39	815.12
46	13-16-1	13.28	161.87	492.30	7.54	1.55	2.18	11.10	139.70	4.40	117.90	1.16	0.33	813.01
47	02-12-1	15.64	204.88	209.20	2.42	0.60	1.55	8.40	39.86	0.73	21.80	5.14	0.98	741.44
48	02-19-1	15.66	190.65	378.70	3.45	0.86	2.49	7.58	40.40	1.23	37.00	4.72	0.50	733.75
49	13-5-1	10.35	194.06	217.25	5.59	2.99	2.65	14.54	92.60	2.89	76.50	2.10	0.89	723.95
50	13-14-1	16.82	231.78	307.10	6.14	1.38	1.68	10.29	91.70	2.91	76.60	2.53	0.75	646.93
51	13-17-1	19.90	221.18	212.65	3.96	1.55	4.32	15.55	64.10	2.54	59.50	3.45	1.04	679.32
52	09-1-1	6.42	153.90	536.10	23.20	2.87	1.80	18.69	142.70	8.74	318.40	1.08	0.29	861.31
53	09-3-2	8.68	195.60	645.40	25.58	1.93	1.59	17.94	157.00	7.87	292.60	1.25	0.30	860.00
54	09-5-1	14.56	217.30	830.00	18.27	1.84	1.69	19.45	160.80	6.96	260.40	1.35	0.26	827.29
55	09-8-1	4.09	142.90	585.00	16.94	2.37	2.01	15.64	107.10	6.40	233.70	1.33	0.24	831.80
56	02-5-1	7.68	157.36	470.80	51.82	2.35	2.52	29.15	202.00	10.90	346.20	0.78	0.33	835.80
	09-1-2	11.49	168.50	336.30	31.51	2.35	1.49	17.49	142.50	7.34	274.70	1.18	0.50	857.10
注：含量单位为10^-6；1~19样品为黑云母花岗岩；20~46样品为二云母花岗岩；47~51样品为白云母花岗岩；52~55样品为黑云母花岗岩闪长岩；56样品为黑云母英云闪长岩.

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